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1990 (1)
1Author    J. Schmidt, H. Gottstein, Scheer, A. ScherzRequires cookie*
 Abstract    Micellar aggregates have been prepared from chloro­ phyll a. Whereas most detergents including non-ionic, zwitterionic and anionic ones, produce aggregates with long-wavelength shifted and enhanced Q Y absorption, the cationic detergents hexadecyl-trimethylammonium-bromide and hexadecyl-pyridiniumchloride produce complexes with opposite traits: The Q Y absorption is shifted to shorter wavelengths, and it is hypochromic. The optical activity is increased as in the long-wave­ length shifted complexes, but the cd bands are non-con­ servative and coincide with the absorption maxima. The complexes are most likely small aggregates o f chloro­ phyll with a changed geometry as compared to the "standard" ones. 
  Reference    Z. Naturforsch. 45c, 729—732 (1990); received January 26 1990 
  Published    1990 
  Keywords    Chlorophyll, Micelles, Detergent, Aggregation, Absorp­ tion, Circular Dichroism, Molecular Orbital 
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 TEI-XML for    default:Reihe_C/45/ZNC-1990-45c-0729_n.pdf 
 Identifier    ZNC-1990-45c-0729_n 
 Volume    45