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'Addition Reactions' in keywords Facet   Publication Year 1978  [X]
Facet   section ZfN Section B  [X]
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1Author    OttoJ. Scherer, Norbert Kuhn, Heribert JungmannRequires cookie*
 Title    Elementorganische Amin/Imin-Verbindungen, XIX [1] Phospha(III)azen-Komplexe des Platins Elementorganic Amino/Imino Compounds, XIX [1] Phospha(III)azene Complexes of Platinum  
 Abstract    Reacting Zeise's salt with the phospha(III)azene (R3C)(R3Si)N-P = N-CR3 (R = CH3) (1) one gets the platinum phospha(III)azene complex (2), Cl2PtI<2 (L = 1). 2 adds water and methanol to the P=N bond of the phospha(III)azene ligand with formation of 3, Cl2Pt(PRR2 1)2 (R = (CH3)3SiO, R 1 = (CH3)3CNH) and 4, Cl2Pt(PRR 1 R 2)2 (R = CH30, R 1 = (CH3)3CNH, R2 = (CH3)3SiNC(CH3)3). 2, 3 and 4 have trans configuration, 4 also forms a mixture of the meso and d, 1 isomers. For 2 a P-a coordination of the phospha(III)-azene ligand is proposed. Die inzwischen in größerer Anzahl bekanntge-wordenen Phospha(III)azene des Typs A [la] /Py -W X N-A I 
  Reference    Z. Naturforsch. 33b, 1321—1324 (1978); eingegangen am 12. Juli 1978 
  Published    1978 
  Keywords    Synthesis, Addition Reactions, Diastereoisomers, NMR 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-1321.pdf 
 Identifier    ZNB-1978-33b-1321 
 Volume    33