1 | Author | Karl Hensen, Michael Dräbing | Requires cookie* |
Title | Thermodynamische Betrachtungen von Schmelzdiagrammen einiger Systeme aus Methylchlorsilanen und Lutidinen ![]() | ||
Abstract | A thermodynamic interpretation of the liquidus curves of some methyltrichloro-respectively dimethyldichlorosilane/lutidine-systems is given. Based on certain approximations it was possible to fit thermodynamic functions to the experimental results to obtain the excess datas of binary systems. A comparison between the models of Redlich-Kister, Wilson and the NRTL-formalism for the free excess enthalpy of binary mixtures is given. | ||
Reference | Z. Naturforsch. 45a, 1158—1164 (1990); eingegangen am 1. Juni 1990 | ||
Published | 1990 | ||
Keywords | Phase diagrams, Methylchlorosilanes, Lutidines, Addition compounds, Thermodynamic excess functions | ||
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