| 1 | Author
| K. Wieghardt, S. Brodka, K. Peters, E. M. Peters, A. Simon | Requires cookie* | | Title
| Säure-Base-Eigenschaften des zyklischen Triamins N,N',N"-Trimethyl-l,4,7-triazacyclononan: Die Kristallstruktur seiner monoprotonierten Form [C9H22N3KCIO4) Acid-Base Properties of the Cyclic Triamine N,N\N"-Trimethyl-l,4,7-triazacyclononane and Crystal Structure of its Monoprotonated Form [C 9 H 2 2N 3 ](C10 4 )  | | | Abstract
| The crystal structure of the monohydroperchlorate of N,N',N"-trimethyl-l,4,7-triazacyclo-nonane, [C 9 H 2 2N3](C10 4), has been determined by single crystal X-ray diffraction. The acidic proton of the cation is bonded to one amine nitrogen and it forms hydrogen bonds to the other two N-atoms in agreement with a proposed model, which has been invoked to interpret successive protonation constants of cyclic triamines. The salt [Me 6 [9]aneN 3 ](BF 4)3 has also been prepared. | | |
Reference
| Z. Naturforsch. 42b, 279—281 (1987); eingegangen am 8. Oktober/24. November 1986 | | |
Published
| 1987 | | |
Keywords
| Macrocyclic Triamine, X-Ray, Acid-Base Properties | | |
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| default:Reihe_B/42/ZNB-1987-42b-0279.pdf | | | Identifier
| ZNB-1987-42b-0279 | | | Volume
| 42 | |
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