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'Acetonitrile' in keywords Facet   section ZfN Section B  [X]
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1995 (1)
1993 (1)
1976 (1)
1Author    Erik Lüddecke, Heinz Mauser, Jürgen PolsterRequires cookie*
 Title    Photochemical Reactions of 1-Hydroxy-1 H-benzotriazole and its Salts in Acetonitrile  
 Abstract    The photoreactions of 1-hydroxy-1H-benzotriazole and its salts are spectrophoto-metrically analyzed dependent on oxygen concentration in acetonitrile. Quantum yields have been determined. 
  Reference    (Z. Naturforsch. 31b, 1438—1439 [1976]; eingegangen am 2. Juli 1976) 
  Published    1976 
  Keywords    Kinetics, Photoreaction, Benzotriazole, Spectrophotometric, Acetonitrile 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-1438_n.pdf 
 Identifier    ZNB-1976-31b-1438_n 
 Volume    31 
2Author    Saim Özkar, Zahide ÖzerRequires cookie*
 Title    3C NMR Spectroscopic Study of Pentacarbonylacetonitrilemetal(O) Complexes of the Group 6 B Elements  
 Abstract    The com plexes M (CO)5(C H 3C N) (M: Cr, M o, W) were obtained from the substitution o f TH F in M (C O)5(TH F) which has been generated by photolysis o f M(CO)6 in T H F and characterized by using IR , 'H N M R and l3C N M R spectrosco­ pies. The acetonitrile ligand is found to be N -bonded to the M (CO)5-moiety with a local C4v-symmetry. The effect o f the acetonitrile ligand on the metal-carbonyl bonding was discussed in terms o f l3C N M R chemical shifts. 
  Reference    Z. Naturforsch. 48b, 1431 (1993); received M ay 17 1993 
  Published    1993 
  Keywords    Chromium, M olybdenum, Tungsten, Carbonyl, Acetonitrile 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-1431_n.pdf 
 Identifier    ZNB-1993-48b-1431_n 
 Volume    48 
3Author    F. C. Feyen, P. K. BurkertRequires cookie*
 Title    Nitrogen-15 and Boron-11 NMR Spectroscopy of the System Acetonitrile / H-ZSM-5  
 Abstract    The interaction of adsorbed acetonitrile with microporous [Si,Al]-ZSM -5 and [Si,B]-ZSM-5 was investigated by solid state NMR. l:iN-CP MAS NM R of the system H-[Si,Al]-ZSM -5 / acetonitrile clearly shows the Bronsted and Lewis acid site interactions. Different coordina­ tion types of the complex ZSM-5/MeCN are considered. The accessibility o f the acid sites of [Si,B]-ZSM -5, a material structurally analogous to zeolite ZSM-5, was studied by " B-M AS NM R. The com plexation o f acetonitrile at the BO^ sites gives a narrow line at -4 ppm. In contrast to hydration phenomena of ZSM-5, the experiments show that acetonitrile is not capable of interacting with all of the BO 3 sites of the borosilicate, presumably due to steric effects. 
  Reference    Z. Naturforsch. 50b, 1753—1758 (1995); received May 4 1995 
  Published    1995 
  Keywords    15N NM R Spectra, n B NM R Spectra, ZSM-5, Acetonitrile, Acid Sites 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1753.pdf 
 Identifier    ZNB-1995-50b-1753 
 Volume    50