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'Acetonitrile Solvate o f Osmium Tetrachloride' in keywords
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1990 (1)
1Author    Hans-W Alter, Swidersky, K. Urt DehnickeRequires cookie*
 Title      
 Abstract    [OsC14(C H 3C N)2] • 1/2C H 3CN has been pre­ pared by the reaction o f OsCl5 with acetonitrile in a slow reaction at room temperature, forming red, moisture sensitive crystals. The com pound was characterized by IR spectroscopy as well as by an X-ray structure determination. Space group Pnma, Z = 4, 1281 observed unique reflexions, R = 0.031. Lattice dimensions at 20 °C: a = 1032.5(5), b = 1356.0(7), c = 975.9(5) pm. The complex has a molecular structure, in which the osmium atom is octahedrally coordinated by four chlorine atoms and by two N -atom s o f the cis-coordinated acetonitrile molecules. The included C H 3C N m olecules are disordered in two posi­ tions. 
  Reference    Z. Naturforsch. 45b, 1210—1212 (1990); eingegangen am 26. Februar 1990 
  Published    1990 
  Keywords    Acetonitrile Solvate o f Osmium Tetrachloride, Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/45/ZNB-1990-45b-1210_n.pdf 
 Identifier    ZNB-1990-45b-1210_n 
 Volume    45