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1983 (1)
1Author    Martin Hoch, Dieter RehderRequires cookie*
 Title    Carbonylniobium Chemistry, IV [1] Derivatives of ^ 5 -C5H5Nb(CO)4 with Tridentate Phosphines  
 Abstract    The photo-induced reaction between CpNb(CO)4 and Ph2P(CH2)2PR(CH2)2PPh2 (L; R = Ph, Cy) yields the chelated five-membered ring complexes cis-[CpNb(CO)2L] (two isomers in the case of R = Cy). The uncordinated PPI12 group reacts with CpNb(CO)3THF to form CpNb(CO)2(ia-L)CpNb(CO)3. IR, 31 P and 93 Nb NMR spectra are discussed and compared with corresponding data of the analogous vanadium complexes. 
  Reference    Z. Naturforsch. 38b, 446—448 (1983); received December 17 1982 
  Published    1983 
  Keywords    Carbonylniobium, 1, 4, 7-Triphosphaheptanes, 31 P NMR, 93 Nb NMR 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0446.pdf 
 Identifier    ZNB-1983-38b-0446 
 Volume    38