| | 1 | Author
| New Monocyclic Acyloxyfluoroboranes, Herbert Binder, Walter Matheis, Hans-Jörg Deiseroth, Han Fu-Son, ProfH. Dr, W. Binder, Matheis | Requires cookie* | | | Title
| Über neue monocyclische Acyloxyfluoroborane 2.2.6.6-Tetrafluoro-1.4-dialkyl-1.3.5-trioxa-1.6-diboracyclohexene: Darstellung, Molekül-und Kristallstruktur  | | | | Abstract
| Acyloxyfluoroboranes Trimeric alkoxydifluoroboranes (F2BOR)3 (2) react with organic acid anhydrides by substitution of a ring group OR forming monocyclic acyloxyfluoroboranes of the type 2,2,6,6-tetrafluoro-l,4-dialkyl-l,3,5-trioxa-2,6-diboracyclohexene (3). The X-ray crystal structure determination of 3a shows two conformational isomers: two planar and two non-planar six-membered rings are present in the unit cell. The ring conformation is influenced by weak intermolecular H — F interactions. | | | |
Reference
| Z. Naturforsch. 38b, 554—558 (1983); eingegangen am 15. November 1982/26. Januar 1983 | | | |
Published
| 1983 | | | |
Keywords
| 6, 6-Tetrafluoro-l, 4-dialkyl-l, 3, 5-trioxa-2, 6-diboracyclohexenes: Synthesis, Molecular and Crystal Structure | | | |
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| default:Reihe_B/38/ZNB-1983-38b-0554.pdf | | | | Identifier
| ZNB-1983-38b-0554 | | | | Volume
| 38 | |
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