| | 1 | Author
| A. Rto, M. Aaninena, R. Ené, T. B. Oeré, Tristram Chivers0, M. Asood Parvezc | Requires cookie* | | | Title
| Preparation and X-Ray Structure of 4-N,N'-Bis(trimethylsilyl)- amino-3,5-diisopropylphenylselenium Trichloride  | | | | Abstract
| The reaction of SeCU or SeCF with /V,/V'-bis(trimethylsilyl)-2,6-diisopropylaniline occurs not at the nitrogen atom but by electrophilic aromatic substitution at C-4 of the phenyl ring to give [(CH3)3Si]2NC6 H2('Pr:)SeCl3, which crystallizes as the chloro-bridged dimer in the triclinic system, space group P i, a -10.2598(17), b = 13.665(3), c = 9.7838(10) A, a = 90.056(13), ß = 102.439(11), 7 = 70.922(14)°, V = 1262.3(4) A \ Z = 1. The dimer contains an essentially planar CUSe^-Cl^SeCU unit, with trans apical (Me3SihNC6H2('Pr)2 groups, resulting in approximately square pyramidal geometry at Se. The bridging Se-Cl distances are unequal at 2.587(2) and 2.749(2) A. | | | |
Reference
| Z. Naturforsch. 54b, 1170—1174 (1999); received April 22 1999 | | | |
Published
| 1999 | | | |
Keywords
| Crystal Structure, 2, 6-Diisopropylaniline, Aryl Selenium Trichloride, Bridging Chloride, NMR Data | | | |
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| default:Reihe_B/54/ZNB-1999-54b-1170.pdf | | | | Identifier
| ZNB-1999-54b-1170 | | | | Volume
| 54 | |
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