1 | Author | Regine Herbst, KatteshV. Katti, HerbertW. Roesky, GeorgeM. Sheldrick | Requires cookie* |
Title | Synthese und Struktur des ersten Cyclophosphazens mit einer M etall—Metall-Bindung im Ringgerüst Synthesis and Structure o f the First Cyclophosphazene Containing a Metal —Metal Bond within the Ring Skeleton ![]() | ||
Abstract | The reaction of [H2NPPh2NPPh2N H 2]Cl (1) with WClft (2) proceeds with formation of NPPh2NPPh2NWCl3 (3) and HCl,N6P4Ph8W 2 (4). 3 is the main product of this reaction. 4 was characterized by an X-ray structure determination. 4 contains a seven and a six-membered phos-phorus-nitrogen ring with a W —W bond of 269.2 pm. | ||
Reference | Z. Naturforsch. 42b, 1387 (1987); eingegangen am 22. Juni/6. August 1987 | ||
Published | 1987 | ||
Keywords | Tungsten, 6;r-Systems, X-Ray, Phosphorus-Nitrogen Compound | ||
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