| | 1 | Author
| Christa Pomp, Stefan Drüeke, Heinz-Josef Küppers, Karl Wieghardt, Carl Krüger, Bernhard Nuber, Johannes Weiss | Requires cookie* | | | Title
| Synthese  | | | | Abstract
| von [LRe(CO) 3 ] + -Komplexen mit makrocyclischen Liganden Die Kristallstrukturen von 1,4,7-TriazacycIononan-tricarbonyl-rhenium(I)-thiocyanat und 1,4,7-Trithiacyclononan-tricarbonyl-rhenium(I) -bromid-hemihy drat Synthesis of [LRe(CO) 3 ]" Complexes with Macrocyclic Ligands The Crystal Structures of l,4,7-Triazacyclononane-tricarbonyl-rhenium(I) Thiocyanate and of l,4,7-Trithiacyclononane-tricarbonyl-rhenium(I) Bromide Hemihydrate The tridentate macrocyclic ligands 1,4,7-triazacyclononane, its thia analogue 1,4.7-trithia-cyclononane, l-oxa-4,7-diazacyclononane, and N,N',N"-trimethyl-l ,4,7-triazacyclononane react with Re(CO) 5 Br in dimethylformamide to yield colorless, air-stable [LRe(CO) 3 ]Br complexes (L = tridentate macrocycle). With Mn(CO) 5 Br only the cyclic amines react to af-ford yellow-orange [LMn(CO),]Br complexes whereas 1.4,7-trithiacyclononane does not give stable complexes of manganese. The crystal structures of [([9]aneN 3)Re(CO) 3 ](NCS) and [([9]aneS 3)Re(CO) 3 ]Br-1/2 H : 0 have been determined. The former crystallizes in the orthorhom-bic space group Pbca (a = 12/763(4), b = 12.662(5), c = 17.472(9) Ä; Z = 8); whereas the latter crystallizes in the monoclinic space group P2,/c (a = 9.444(1). b = 11.797(2), c = 28.095(3) Ä. ß = 90,86(1); Z = 8). | | | |
Reference
| Z. Naturforsch. 43b, 299—305 (1988); eingegangen am 9. Oktober 1987 | | | |
Published
| 1988 | | | |
Keywords
| Crystal Structure, 1, 4, 7-Triazacyclononane 1, 47-Trithiacyclononane Complexes | | | |
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| default:Reihe_B/43/ZNB-1988-43b-0299.pdf | | | | Identifier
| ZNB-1988-43b-0299 | | | | Volume
| 43 | |
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