| | 1 | Author
| Akinori Shiotani | Requires cookie* | | | Title
| Die Pd-katalysierte oxidative Kupplungsreaktion von Methylbenzoesäuremethylester The Pd-Catalyzed Oxidative Coupling Reaction of Methyl Methylbenzoates  | | | | Abstract
| The Pd-catalyzed oxidative coupling reaction of methyl o-toluate gives, in the presence of a Pd/l,10-phenanthroline(phen)/Cu catalyst, exclusively, the para-linked biphenyldicarboxy-lates 1, 2, and 3. On the other hand, the meta-linked biphenyldicarboxylates 4 and 5, were predominantly formed in a catalyst system of Pd/2,4-pentanedione(acacH)/Cu, and under similar conditions 6 and 7 were also obtained from the coupling reaction of methyl m-toluate and methyl p-toluate, respectively. A reaction scheme has been proposed. | | | |
Reference
| Z. Naturforsch. 49b, 1731—1736 (1994); eingegangen am 21. April 1994 | | | |
Published
| 1994 | | | |
Keywords
| Coupling Reaction, Steric Influence, Palladium, 1, 10-Phenanthroline, 2, 4-Pentanedione | | | |
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| default:Reihe_B/49/ZNB-1994-49b-1731.pdf | | | | Identifier
| ZNB-1994-49b-1731 | | | | Volume
| 49 | |
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