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'4 Dimethylpiperazinium Tetrabromometalates II' in keywords Facet   section ZfN Section B  [X]
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1996 (1)
1Author    Michael Feist, Sergej Trojanov, Erhard KemnitzRequires cookie*
 Title    Die Kristallstrukturen von 1,4-Dimethylpiperazinium-tetrabromo- cobaltat(II) und -zinkat(II), (dmpipzH2) [Mn Br4] (M = Co, Zn)  
 Abstract    The Crystal Structures of 1,4-Dimethylpiperazinium Tetrabromocobaltate(II) and -Zincate(II), (dmpipzH2) [MHBr4] (M = Co, Zn) The compounds (dmpipzH2)[MnBr4] (M = Co, Zn) crystallize at room temperature from equi-molar solutions of 1,4-dimethylpiperazine and MBr2 • n H20 in 3M HBr. (dmpipzH2)[CoBr4] is isotypic with the homologous chlorometalates of Co and Zn and crystallizes in the mono­ clinic space group P2,/m with a = 6.424(3), b = 14.588(6), c = 7.102(6) A, ß = 90.87(6)°, Z = 2. (dmpipzH2)[ZnBr4], however, crystallizes in the monoclinic space group P2,/c with a = 7,605(5), b = 13,760(9), c = 13,286(7) Ä, ß = 93,03(6)°, Z = 4. Both structures con­ tain centrosymmetric cations (dmpipzH2)2+ in the chair form and slightly distorted tetrahedra [MBr4]2~ with a mirror plane in the case ofM = Co. Several distances N- • -Brin both structures are interpreted in terms of N-H- • Br hydrogen bonds which are favoured by the packing in the case of M = Zn. 
  Reference    (Z. Naturforsch. 51b, 9—13 [1996]; eingegangen am 12. Juni 1995) 
  Published    1996 
  Keywords    1, 4-Dimethylpiperazinium Tetrabromometalates(II), Cobalt, Zinc, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0009.pdf 
 Identifier    ZNB-1996-51b-0009 
 Volume    51