| | 1 | Author
| Jörg Fleischhauer3, Sven Gabriel3, Dieter Enders3, Anja Nühring3, Axel Wollmerb | Requires cookie* | | | Title
| CD-Spectroscopic Investigations for the Determination of the Absolute Configuration of a-Alkylated 1,4-CycIohexanedione Derivatives  | | | | Abstract
| The absolute configuration of the conformationally flexible six membered ring system 2-me-thyl-and 2,6-dimethyl-l,4-cyclohexanedione monoethylene acetal was determined by compar ison of measured and calculated CD spectra. The rotational strengths were calculated by means of the CNDO/S-method assuming R at the stereogenic center. The results were compared with the predictions made by the octant rule. The enantiomerically pure material was synthesized via the corresponding SAMP-and RAMP-hydrazones. | | | |
Reference
| Z. Naturforsch. 55b, 1011—1014 (2000); received July 3 2000 | | | |
Published
| 2000 | | | |
Keywords
| 1, 4-Cyclohexanedione Derivatives, Absolute Configuration, CD Spectra | | | |
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| default:Reihe_B/55/ZNB-2000-55b-1011.pdf | | | | Identifier
| ZNB-2000-55b-1011 | | | | Volume
| 55 | |
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