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2000 (1)
1Author    Jörg Fleischhauer3, Sven Gabriel3, Dieter Enders3, Anja Nühring3, Axel WollmerbRequires cookie*
 Title    CD-Spectroscopic Investigations for the Determination of the Absolute Configuration of a-Alkylated 1,4-CycIohexanedione Derivatives  
 Abstract    The absolute configuration of the conformationally flexible six membered ring system 2-me-thyl-and 2,6-dimethyl-l,4-cyclohexanedione monoethylene acetal was determined by compar­ ison of measured and calculated CD spectra. The rotational strengths were calculated by means of the CNDO/S-method assuming R at the stereogenic center. The results were compared with the predictions made by the octant rule. The enantiomerically pure material was synthesized via the corresponding SAMP-and RAMP-hydrazones. 
  Reference    Z. Naturforsch. 55b, 1011—1014 (2000); received July 3 2000 
  Published    2000 
  Keywords    1, 4-Cyclohexanedione Derivatives, Absolute Configuration, CD Spectra 
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 TEI-XML for    default:Reihe_B/55/ZNB-2000-55b-1011.pdf 
 Identifier    ZNB-2000-55b-1011 
 Volume    55