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1981 (1)
1Author    Klaus Burger, Herbert Goth, Eduard BurgisRequires cookie*
 Title    Zum Thermolyseverhalten von 2.2-Dihydro-1.4.2-oxazaphosphol-4-enen, II [1] Eine einfache Synthese für fluorsubstituierte N-Vinylimidoylchloride Thermolysis of 2,2-Dihydro-l,4,2-oxazaphosphol-4-enes, II [1] A Simple Synthesis for Fluorine Substituted N-Vinylimidoyl Chlorides  
 Abstract    3,3-Bis(chlorodifluoromethyl)-2,2,2-trimethoxy-2,2-dihydro-l,4,2-oxazaphosphol-4-enes (2) at room temperature, 3,3-bis(chlorodifluoromethyl)-2,2,2-triphenoxy-2,2-dihydro-l,4,2-oxazaphosphol-4-enes (3) at 140-145 °C undergo cycloelimination of trimethyl, and triphenyl phosphate, respectively, with formation of N-[l-chlorodifluoromethyl-2,2-di-fluoro(vinyl)]-imidoyl chlorides (4) in high yields. 
  Reference    Z. Naturforsch. 36b, 353—358 (1981); eingegangen am 18. November 1980 
  Published    1981 
  Keywords    Phosphorus Compounds, [3 + 2] Cycloreversion Reactions, [1, 4] Chlorine Shift, 2 -Azabuta-1, 3 -dienes 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0353.pdf 
 Identifier    ZNB-1981-36b-0353 
 Volume    36