| | 1 | Author
| Klaus Burger, Herbert Goth, Eduard Burgis | Requires cookie* | | | Title
| Zum Thermolyseverhalten von 2.2-Dihydro-1.4.2-oxazaphosphol-4-enen, II [1] Eine einfache Synthese für fluorsubstituierte N-Vinylimidoylchloride Thermolysis of 2,2-Dihydro-l,4,2-oxazaphosphol-4-enes, II [1] A Simple Synthesis for Fluorine Substituted N-Vinylimidoyl Chlorides  | | | | Abstract
| 3,3-Bis(chlorodifluoromethyl)-2,2,2-trimethoxy-2,2-dihydro-l,4,2-oxazaphosphol-4-enes (2) at room temperature, 3,3-bis(chlorodifluoromethyl)-2,2,2-triphenoxy-2,2-dihydro-l,4,2-oxazaphosphol-4-enes (3) at 140-145 °C undergo cycloelimination of trimethyl, and triphenyl phosphate, respectively, with formation of N-[l-chlorodifluoromethyl-2,2-di-fluoro(vinyl)]-imidoyl chlorides (4) in high yields. | | | |
Reference
| Z. Naturforsch. 36b, 353—358 (1981); eingegangen am 18. November 1980 | | | |
Published
| 1981 | | | |
Keywords
| Phosphorus Compounds, [3 + 2] Cycloreversion Reactions, [1, 4] Chlorine Shift, 2 -Azabuta-1, 3 -dienes | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0353.pdf | | | | Identifier
| ZNB-1981-36b-0353 | | | | Volume
| 36 | |
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