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1999 (1)
1982 (1)
1Author    Bernhard Schreiner, Reinhold Urban, Anastassios Zografidis, Karlheinz Sünkel, Kurt Polborn, Wolfgang Beck, *. Sonderdruckanforderungen, ProfW. Beck, Herrn Professor, LawrenceF. DahlRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, CXXI [1]. Orthopalladierte Enolate aus N-(Diphenylmethylen)-Schiff-Basen von a-Aminosäureestern als ambivalente 1,3-Dipole in [2+3]-Cyclo- additionsreaktionen. Strukturen einer Reihe von Cycloaddukten Metal Complexes of Biologically Important Ligands, CXXI [1]. Orthopalladated Enolates from N-(Diphenylmethylene) Schiff Bases of a-Amino Acid Esters as Ambivalent 1,3-Dipoles in [2+3] Cycloadditions. Structures of a Series of Cycloadducts  
 Abstract    Enolates of ortho-palladated N-(diphenylmethylene) Schiff bases from glycine esters (R3P)Pd[(C6H4)(C6H5)C=N-C(R')=C0 2R] were isolated and have been shown to be ambiva­ lent 1,3-dipoles in [2+3] cycloadditions. Tetracyanoethene, dimethyl acetylene dicarboxylate, dimethyl azodicarboxylate, thiobenzophenone, thione-S, 4-phenyl-l,2,4-triazoline-3,5-dione, diphenyl-ketene and phenylisocyanate are added at the palladium and the enolate (a-C) carbon atoms, whereas methyl propiolate, methyl acrylate, and the methyl esters of maleic and fumaric acid form [2+3] cycloadducts with the «-carbon and the imino carbon atoms of the enolates un­ der mild conditions. The structures of seven cycloadducts were determined by X-ray diffraction analyses. 
  Reference    Z. Naturforsch. 54b, 970—988 (1999); eingegangen am 3. Mai 1999 
  Published    1999 
  Keywords    N-(Diphenylmethylene)glycinate, Enolates, 1, 3-Dipoles, [2+3] Cycloaddition, X-Ray Data 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0970.pdf 
 Identifier    ZNB-1999-54b-0970 
 Volume    54 
2Author    Klaus Burger, Herbert GothRequires cookie*
 Title    Positionsselektivität und Regiochemie bei Abfangreaktionen mit Heterokumulenen Cycloaddition Behaviour of Bis(trifluoromethyl) Substituted Nitrile Ylides [1] Site Selectivity and Regiochemistry of Trapping Reactions with Heterocumulenes  
 Abstract    3,3-bis(trifluoromethyl)-2,2-dihydro-l,4,2-oxazaphosphol-4-enes on thermolysis undergo a 1,3-dipolar cycloreversion reaction with formation of bis(trifluoro-methyl) substituted nitrile ylides and trimethyl phosphate. The nitrile ylides are trapped by N-8ulfinyl aniline, phenyl isocyanate, phenyl isothiocyanate, diphenyl ketene, and carbon disulfide. Site selectivity and regiochemistry of the [3 + 2]cycloaddition reactions are described. The results are compared with those obtained from [3 + 2]cycloaddition reactions of nitrile imines, nitrile oxides, alkyl, and aryl substituted nitrile ylides with heterocumulenes. 
  Reference    Z. Naturforsch. 37b, 473—485 (1982); eingegangen am 30. September 1981 
  Published    1982 
  Keywords    1, 3-Dipolar Cycloreversion Reactions, 2, 2-Dihydro-l, 4, 2-oxazaphosphol-4-enes, Trifluoromethyl Substituted 1, 3-Dipoles, Partially Fluorinated Heterocyclic Compounds 2, 2, 2-Trimethoxy- 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0473.pdf 
 Identifier    ZNB-1982-37b-0473 
 Volume    37