| 1 | Author | WolfPeter Fehlhammer, Bartel Klaus, Dagobert Alfons Völkl, Achatz | Requires cookie* |
| Title | Metallkomplexe funktioneller Isoeyanide, VI [1] Tosylmethyl-, Benzyl-und Benzhydrylisocyanid-Metallverbindungen und ihre Reaktionen mit Nucleophilen und 1.3-Dipolarophilen Metal Complexes of Functional Isocyanides, VI [1] Tosylmethyl-, Benzyl-and Benzhydrylisocyanide Metal Complexes and Their Reactions with Nucleophiles and 1,3-Dipolarophiles  | ||
| Abstract | Metal complexes of the type M(CO)5L (M = Cr, W), MX2L2 (M = Pd, Pt; X = Cl, Br, 1), PtClo(L)PPh3, and [Pt(Cl)(L)(PPh3)2]BF4 have been prepared with L = CNCH2S02C6H4-^CH3, CNCHoPh, and CNCHPho, and reacted with a variety of nucleophiles (NH2CH2C02CH3, CH(CN)2", CH(CN)C02CH3-, OH-) and 1,3-dipolarophiles (CF3CN, CH3O2CCEECCO2CH3, CH2 = CHCN, RNCO (R -CH3, Ph), RCHO (R = i-C3H7, Ph, C6H4-0OH)) to give carbene, a-aminovinyl, and carboxamido complexes, and C2-metallated heterocycles (imidazoles, pyrroles, oxazolos, oxazolines), respectively. Ready de-alkylation occurs of benzhydryl isoeyanide in [Pt(Cl)(CNCHPh2)(PPh3)2]BF4* | ||
| Reference | Z. Naturforsch. 37b, 1044—1053 (1982); eingegangen am 5. Februar 1982 | ||
| Published | 1982 | ||
| Keywords | Transition Metal Complexes of Functionalized Isocyanides, Reactions at Co-ordinated Ligands, Carbene Complexes, 1, 3-Dipolar Cycloadditions | ||
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