| | 1 | Author
| Jörg Münzenberg, HerbertW. Roesky, M. Athias Noltemeyer, Susanne Besser, Regine Herbst-Irmer | Requires cookie* | | | Title
| Synthese und struktureller Vergleich einiger TeIlur(IV)-Iminate Syntheses and Structural Com parison of Some Tellurium(IV) Iminates  | | | | Abstract
| T e -N compounds with Ph;SN and Ph2CN ligands were synthesized by treating TeCl4, TeF4, and ArTeCl3 (Ar = p-M eO C6H4) with the corresponding silylated ligand precursors 1 and 5. The l25Te N M R spectra of the com pounds Cl3TeN SPh2 2, Cl2Te(NSPh2)2 3, ArTe(Cl2)NSPh2 4, Cl2Te(N CPh2)2 6, F2Te(N CPh2)2 7 and ArTe(Cl2)N C Ph2 8 have been deter mined. The X-ray structures of the com pounds 2 -Pyridin, 3 and 8 show Cl-bridged dimers in the solid state, while 6 and 7*0.5 MeCN are monomeric. In the diphenylsulfiminates 2-Pyridin and 3 short T e -N bond distances are found. | | | |
Reference
| Z. Naturforsch. 48b, 199—208 (1993); eingegangen am 3. September 1992 | | | |
Published
| 1993 | | | |
Keywords
| Diphenylsulfiminates, Diphenylketiminates, X-Ray, , 25Te N M R Spectra | | | |
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| default:Reihe_B/48/ZNB-1993-48b-0199.pdf | | | | Identifier
| ZNB-1993-48b-0199 | | | | Volume
| 48 | |
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