| | 1 | Author
| Z. Naturforsch | Requires cookie* | | | Title
| Über Erdalkalimetallverbindungen des l,l-Dicyanoethylen-2,2-dithiolats, III+ Die Kristallstruktur von SrS2C4N2 * 5 H20  | | | | Abstract
| By reaction of CS2 with m aleonitrile in presence of sodium ethanolate in ethanol, N a2S2C4N 2 is obtained. SrS2C4N2-5 H 20 was synthesized by reaction of Sr(NCS) 2 with N a2S2C4N2 in ethanol. It crystallizes monoclinically, space group P2!/c, with a = 9.201(2), b — 9.990(6), c = 14.605(5) Ä,/3 = 122.3(3)°, Z = 4. The com pound is isotypical with CaS2C4N2-5 H 20 . A structural model based on equivalent metal positions was refined to R -0.057. The crystal structure contains layers of nearly planar [S2C = C (C N)2]2' anions held together by interspersed Sr2+ cations in a tricapped trigonal prismatic surrounding of 6 0 and 3N atoms. The S atom s of the ligand are not included in the coordination sphere of Sr2+ but are involved in several O — H -S hydrogen bonds. | | | |
Reference
| Z. Naturforsch. 41b, 1206—1210 (1986); eingegangen am 1. April/26. Juni 1986 | | | |
Published
| 1986 | | | |
Keywords
| Strontium -l, l-dicyanoethylene-2, 2-dithiolate P entahydrate, Synthesis, Crystal Structure | | | |
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| default:Reihe_B/41/ZNB-1986-41b-1206.pdf | | | | Identifier
| ZNB-1986-41b-1206 | | | | Volume
| 41 | |
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