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'2 H ydrazine bis dithiocarboxylates' in keywords Facet   section ZfN Section B  [X]
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1984 (1)
1Author    RainerM. Attes, Bernd FüsserRequires cookie*
 Title    Salze der 1.2-Hydrazin-bis(dithiocarbonsäure): Darstellung, Schwingungsspektren und Struktur Preparation, V ibrational Spectra and Structure of Alkahm etal Salts of the l,2-H ydrazine-bis(dithiocarboxylic Acid)  
 Abstract    The following salts of the l,2-hydrazine-bis(dithiocarboxylic acid) have been prepared: Mi[S->CNH —NHCS^], M = N a, K and M3[S->CN-NHCS2], M — Na, K. In the solvated crystals K2 1S2C N H -N H C S 2 '] • 4 C H 3O H (a = 718.0(5), b = 1329.3(8), c = 937.7(9) pm , ß = 109.26(6)°, space group C2/m , Z = 2) the [S2C N H -N H C S 2]2" ion possesses crystallographic C2h sym metry, i.e. a trans planar structure with a N -N bond length of 139.2(3) pm. V ibrational spectra indicate a lower sym metrical anion in the unsolvated crystals. In the trianion [S2CN —N HCS2]3_ the C —N stretching vibrations are observed at 1400 and 1310 cm" 1. 
  Reference    (Z. Naturforsch. 39b, 1 [1984]; eingegangen am 14. Septem ber 1983) 
  Published    1984 
  Keywords    l, 2-H ydrazine-bis(dithiocarboxylates), Preparation, Crystal Structure, V ibrational Spectra 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0001.pdf 
 Identifier    ZNB-1984-39b-0001 
 Volume    39