| | 1 | Author
| E. K. Yudin, K. V. Domasevitch, E. B. Rusanov | Requires cookie* | | | Title
| Crystal and Molecular Structure of Isonitrosomalonodiamido- (2,2-dipyridyl)copper(II), Chloride Monohydrate [Cu(Dipy){ONC(CONH2)2}Cl] H20  | | | | Abstract
| The crystal and molecular structure of the complex [Cu(Dipy){NDA}Cl] • H 20 , where (NDA) = {ONC(CONH2)2}~ anion (space group P I, triclinic, with a = 7.834(1), b = 9.923(1), c = 9.952(1)A, a = 93.60(1), ß = 93.65(1), y = 92.72(1)°, Z = 2) has been determined from X-ray diffraction data. The structure was refined to R -0.029 for 2243 reflections with I>3ct(I). The coordination polyhedron of Cu2+ can be described as a distorted square pyra mid with a chlorine atom in the apex, and with the central atom situated 0.258(3) A above the base of the pyramid towards the chlorine atom. The complicated system of hydrogen bonding involving the water of crystallization connects copper complex units in to the chains in the c direction. | | | |
Reference
| Z. Naturforsch. 50b, 864—866 (1995); received O ctober 17 1994 | | | |
Published
| 1995 | | | |
Keywords
| Copper(II), Oximes, 2, 2-Dipyridyl, X-Ray Spectra | | | |
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| default:Reihe_B/50/ZNB-1995-50b-0864.pdf | | | | Identifier
| ZNB-1995-50b-0864 | | | | Volume
| 50 | |
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