| | 1 | Author
| WolfgangK. Läuia, Susanne Schoger2, Martin Niegerb | Requires cookie* | | | Title
| Synthesis and Crystal Structure of Perhydro-l,4-benzoxazino[2,3-n]phenoxazine  | | | | Abstract
| The oxidation of fra«s-2-aminocyclohexanol with nitrobenzene in the presence of catalytic amounts of iron inter alia yields perhydro-l,4-benzoxazino[2,3-n]phenoxazine (1). This com pound has been characterized analytically, spectroscopically and by X-ray diffraction. It is postulated that the oxidation of the 2-aminoalcohol leads to the intermediate formation of a 1,2-dione. The direct synthesis of 1 from trans-2-aminocyclohexanol and 1,2-cyclohexandione supports this hypothesis. | | | |
Reference
| Z. Naturforsch. 52b, 801—804 (1997); eingegangen am 14. Oktober 1996 | | | |
Published
| 1997 | | | |
Keywords
| Nitrobenzene, Reduction, Aniline, 2-Aminoalcohols, Catalysis | | | |
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| default:Reihe_B/52/ZNB-1997-52b-0801.pdf | | | | Identifier
| ZNB-1997-52b-0801 | | | | Volume
| 52 | |
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