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'18 Crown 6' in keywords Facet   Publication Year 1997  [X]
Facet   section ZfN Section B  [X]
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1Author    JuliaA. Manskaya, VolodimirN. Kokozay, KonstantinV. DomasevitchRequires cookie*
 Title    Crystal Structure of an Ammonium Dithiocyanatocuprate(I) Complex with 18-Crown-6, [NH4(18-Crown-6){Cu(NCS)2}] Obtained from Zero Valent Metal  
 Abstract    The new macrocyclic dithiocyanatocuprate(I) complex [NH4(18-crown-6){Cu(NCS)2}] has been prepared using a direct method of interaction and characterized by X-ray crystallogra­ phy (orthorhombic, space group Cmc2i, with a = 12.453(2), b = 21.650(4), c = 8.151(2) A, V = 2197.6(8) Ä3, Z = 4 , 1 (F) = 0.054; wR2(F2) = 0.141 for 972 unique reflections with I > 2<r(I) and /?1(F) = 0.082; w/?2(F2) = 0.210 for all 1098 unique reflections). The lattice comprises complex cations [NH4(18-crown-6)]+ and infinite polymeric anions [Cu(NCS)2]-of a one-dimensional zig-zag structure. The copper atoms adopt three-fold coordination [CuN^S] (Cu-N 1,89(1), 1,90(1) A; Cu-S 2.278(4) A). 
  Reference    Z. Naturforsch. 52b, 1311—1314 (1997); received 
  Published    1997 
  Keywords    18-Crown-6, Copper(I), Thiocyanate, Synthesis, X-Ray 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-1311.pdf 
 Identifier    ZNB-1997-52b-1311 
 Volume    52 
2Author    P. E. Te, G. JonesRequires cookie*
 Title    Polysulfonylamine, XC [1] Carbonsäure-Dimere, Wasser-Dimere und 18-Krone-6-Moleküle als Baugruppen eines supramolekularen Kettenpolymers: Darstellung und Struktur von (CH2CH20 ) 6 * 4 H20 * 2 H N (S 02C6H4-4 -C 0 0 H ) 2  
 Abstract    P o ly su lfo n y lam in es, X C [1] C a rb o x y lic A cid D im ers, W a te r D im e rs a n d 18-C row n-6 M o lecu les as B u ild in g B lo cks in a S u p ra m o le c u la r C hain P o ly m er: S ynth esis a n d S tru c tu re o f (C H 2C H 20) 6 • 4 H 20 • 2 H N (S 0 2C 6H 4-4 -C 0 0 H) 2 K a rn a W ijaya*, O liv e r M oers, A rm a n d B lasc h ette 
  Reference    Z. Naturforsch. 52b, 997—1002 (1997); eingegangen am 23. Mai 1997 
  Published    1997 
  Keywords    Di(4-carboxybenzenesulfonyl)amine, 18-Crown-6, Carboxylic Acid Dimer, Water Dimer, Ternary Complex of Uncharged Molecules 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0997.pdf 
 Identifier    ZNB-1997-52b-0997 
 Volume    52