| | 1 | Author
| Michael Schäfer, Jürgen Pebler, Beatrice Borgsen, Frank Weller, K. Urt Dehnicke | Requires cookie* | | | Title
| 21Sb-Mössbauer-spektroskopische und strukturchemische Untersuchungen an Kronenetherkomplexen SbX3(15-Krone-5) mit X = F, Cl, Br, I. Eine Analyse der Orbitalbesetzungszahlen 12lSb-M össbauer-Spectroscopic and Structural Investigations on Crown Ether Complexes SbX3(15-Crown-5) with X = F, Cl, Br, I. A Population Analysis Crown Ether C om plexes SbX3(15-crown-5)  | | | | Abstract
| The crown ether complexes SbX3(15-crown-5) with X = F, Cl, Br, and I have been prepared by reactions o f 15-crown-5 with the corresponding antimony trihalides in acetonitrile solu tions. The com pounds were characterized by IR spectroscopy as well as by l21Sb-M össbauer spectroscopy. A m ethod o f orbital population analysis utilizing both M össbauer isomer shifts and quadrupole coupling has been developed for Sb(III) antimony halides and their crown ether com plexes. SbF 3(l 5-crown-5) was also characterized by an X-ray structure determination: Space group P 2 ,/«, Z = 4, 3628 observed unique reflexions, R = 0.032. Lattice dim ensions at 19 °C: a = 891.54(6), b = 1277.26(6), c = 1277.66(7) pm, ß = 95.029(4)3. The com plex has a molecular structure in which the antimony atom is surrounded by three F-atom s with mean bond lengths o f 192.4 pm and by the five oxygen atom s o f the crown ether molecule with mean bond lengths o f 293.9 pm. | | | |
Reference
| Z. Naturforsch. 45b, 1243—1250 (1990); eingegangen am 5. März/9. Mai 1990 | | | |
Published
| 1990 | | | |
Keywords
| Syntheses, IR Spectra, 12lSb-M össbauer Spectra, Crystal Structure | | | |
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| ZNB-1990-45b-1243 | | | | Volume
| 45 | |
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