| | 1 | Author
| W. Preetz, M. G. Hake | Requires cookie* | | | Title
| Darstellung, "B-NMR-und Schwingungsspektren der ctoso-Hexaborate |B6(SCN)6]J-und [B6(SeCN)6]2  | | | | Abstract
| On treatment o f [N(C4H 9)4][B6H 7] with (S C N)2 or (SeC N)2 in dichloromethane in the pres ence o f solid KOH the hexaborates [N(C4H 9)4]2[B6(SC N)6] and [N(C4H9)4]2[B6(SeC N)6] are formed. The octahedral structure for the B6 cage is proven by "B N M R spectroscopy. The chemical shifts in relation to BF3 • OEt2 o f —9,7 (SC N) and -10,2 ppm (SeC N) show the influ ence o f -I and +M effects o f the substituents. The S(Se) coordination is deduced from vibra tions within the substituents: vCN is observed at frequencies higher than 2100 cm -1 in the IR and Raman spectra, vcs at 662 and vcs at 556 cm "1 (intense IR bands). | | | |
Reference
| Z. Naturforsch. 47b, 1119—1121 (1992); eingegangen am 8. April 1992 | | | |
Published
| 1992 | | | |
Keywords
| Hexathiocyanatohexaborate, H exaselenocyanatohexaborate, 11B N M R Spectra, IR Spectra, Raman Spectra | | | |
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| default:Reihe_B/47/ZNB-1992-47b-1119.pdf | | | | Identifier
| ZNB-1992-47b-1119 | | | | Volume
| 47 | |
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