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1985[X]
1Author    Franz Dallacker, Thomas Böhmel, W. Ilhelm Müllners, HeinrichM. ÜckterRequires cookie*
 Title    Amin-carbamoyl-10B-boran, Darstellung und biologische Eigenschaften Amine-carbamoyl-dihydro-10B-borane, Preparation, and Biological Properties  
 Abstract    The chemical section deals with the synthesis of sodiumcyano-"'B-borhydride (3) from l0B-boric acid trimethyl ester (1) via sodium-inB-borhydride (2). By converting 3 with trimethylammonium chloride, trimethylamine-cyano-10B-borane (4) is formed which, via nitrilium tetrafluoroborate 5, is transformed by water to Trimethylamine-carboxy-dihydro-luB-borane (6). Trimethylamine-ethoxycarbonyl-dihydro-l()B-borane (8b) and amine-carbamoyl-dihydro-"'B-borane (8c) can be synthesized from the imidazolid 8a. In the biological section an orientation to the toxicity and the tumor affinity of the compounds 6, 7. and 8c are described. Further the possibility is shown by achieving a maximal concentration of 10B-boron in the tumor whilst at the same time retaining as low a concentration of 1()B-Boron as possible in the surrounding tissue. 
  Reference    Z. Naturforsch. 40c, 344 (1985); received March 4/April 12 1985 
  Published    1985 
  Keywords    1(, B-Boron, Neutron Capture Therapy, Amine-carboxy-dihydro-'°B-borane 
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 TEI-XML for    default:Reihe_C/40/ZNC-1985-40c-0344.pdf 
 Identifier    ZNC-1985-40c-0344 
 Volume    40 
2Author    Richard Neidlein, Reiner Gottfried, Alfred Gieren, Carsten-P Kaerlein, Thomas HübnerRequires cookie*
 Title    Kupplungsreaktionen von Diazoniumsalzen mit 3-ferf-Butoxy- l,6-methano[10]annulen und Röntgenstrukturanalyse eines Vertreters Coupling Reactions of Diazonium Salts with 3-terr-Butoxy-l,6-methano[10]annulene and X-Ray Structure Analysis of one Compound  
 Abstract    The syntheses of 5a—c by coupling reactions of 3-terr-butoxy-l,6-methano[10]annulene with different aryldiazonium salts as well as their spectroscopic properties are described; an X-ray structure analysis of 5c is reported. 
  Reference    Z. Naturforsch. 40b, 193—198 (1985); eingegangen am 20. August 1984 
  Published    1985 
  Keywords    Syntheses with Coupling Reactions, 1, 6-Methano[10]annulenylarylhydrazones, X-Ray, Bonding Relationships 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0193.pdf 
 Identifier    ZNB-1985-40b-0193 
 Volume    40 
3Author    MichaelC. MoschidisRequires cookie*
 Title    Synthesis of l,2-Dipalmitoyloxypropyl-3-(2-ammoniumethyl) Phosphinate  
 Abstract    The total synthesis of l,2-dipalmitoyloxypropyl-3-(2-ammoniumethyl) phosphinate, the phos-phino-analog of phosphatidyl ethanolamine is described. The phosphinate analog of phosphatidyl ethanolamine has been prepared by an Arbusov type of reaction between a diacyl-glycerol bromohydrin and 2-bromo-ethylphosphonic acid dimethyl ester for 48 h at 178 °C, followed by a reaction with aq. ammonia to yield the final product. The product was characterized by elemental analysis, phosphono-phosphorus determinations and IR spectroscopy. 
  Reference    Z. Naturforsch. 40c, 595—598 (1985); received April 22 1985 
  Published    1985 
  Keywords    Phosphinolipids, Phosphatidyl Ethanolamine, 1, 2-Dipalmitoyl-sn-glycerol Bromohydrin, Phos-phino Analog of Phosphatidyl Ethanolamine 
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 TEI-XML for    default:Reihe_C/40/ZNC-1985-40c-0595.pdf 
 Identifier    ZNC-1985-40c-0595 
 Volume    40