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1978 (1)
1Author    Krystyna Lesiak, WojciechJ. StecRequires cookie*
 Title    The Stereochemistry of P-N Bond Cleavage in the Staudinger -Wittig-type Reaction of 2-Anilido-3,4-dimethyl-5-phenyl-l,3,2-oxazaphospholidine-2-thiones  
 Abstract    Both isomers of 2-anilido-3,4-dimethyl-5-phenyl-l,3,2-oxazaphospholidine-2-thiones (2 a and 2 b) derived from (—)ephedrine were obtained and converted to corresponding 2-thiomethyl derivatives (3 a and 3 b). The Staudinger-Wittig-type reaction of P-N bond cleavage was found to proceed with full retention of configuration at P-atom involved into five-membered ring system. 
  Reference    Z. Naturforsch. 33b, 782—785 (1978); received March 28 1978 
  Published    1978 
  Keywords    1, 3, 2-Oxazaphospholidines, (—)Ephedrine, Thioanilides, Thioesters, Stereochemistry 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0782.pdf 
 Identifier    ZNB-1978-33b-0782 
 Volume    33