| | 1 | Author
| Krystyna Lesiak, WojciechJ. Stec | Requires cookie* | | | Title
| The Stereochemistry of P-N Bond Cleavage in the Staudinger -Wittig-type Reaction of 2-Anilido-3,4-dimethyl-5-phenyl-l,3,2-oxazaphospholidine-2-thiones  | | | | Abstract
| Both isomers of 2-anilido-3,4-dimethyl-5-phenyl-l,3,2-oxazaphospholidine-2-thiones (2 a and 2 b) derived from (—)ephedrine were obtained and converted to corresponding 2-thiomethyl derivatives (3 a and 3 b). The Staudinger-Wittig-type reaction of P-N bond cleavage was found to proceed with full retention of configuration at P-atom involved into five-membered ring system. | | | |
Reference
| Z. Naturforsch. 33b, 782—785 (1978); received March 28 1978 | | | |
Published
| 1978 | | | |
Keywords
| 1, 3, 2-Oxazaphospholidines, (—)Ephedrine, Thioanilides, Thioesters, Stereochemistry | | | |
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| default:Reihe_B/33/ZNB-1978-33b-0782.pdf | | | | Identifier
| ZNB-1978-33b-0782 | | | | Volume
| 33 | |
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