| 1 | Author | W. Preetz, G. Rimkus | Requires cookie* |
| Title | Darstellung von trans-[PtCl4Br2] 2 -und [PtClsBr] 2 - durch oxidative Addition an [PtCl4] 2 ~ Preparation of Jrarwi-[PtCl4Br2] 2 -and [PtCl5Br] 2 -by Oxidative Addition to [PtCl4] 2 ~  | ||
| Abstract | The oxidative addition of Br2 to [PtCl4] 2-in HBr yields almost pure frans-[PtCl4Br2] 2-, in HCl nearly pure [PtClsBr] 2-, and in CH2C12 by a quantitative and stereospecific reaction completely pure £ram-[PtCl4Br2] 2 ~. This is confirmed by ion exchange chromatography on diethylaminoethyl cellulose and by analysis of the vibrational spectra in comparison with the IR and Raman spectra of the well-known species of the series [PtClnBr6-n] 2_ , n = 0-6. The literature concerning £rans-[PtCl4Br2] 2 ~ and other mixed ligand complexes is critically discussed. | ||
| Reference | Z. Naturforsch. 38b, 442—445 (1983); eingegangen am 8. Dezember 1982 | ||
| Published | 1983 | ||
| Keywords | Oxidative Addition, £rans-Tetrachlorodibromoplatinate(IV), Pentachlorobromoplatinate(IV), IR Spectra, Raman Spectra | ||
| Similar Items | Find | ||
