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2001 (1)
1Author    Cungen Zhang, Christoph Janiak, Horst BrombacherRequires cookie*
 Title    Structural Influence of Hydrogen Bonding and ^r-Stacking in fra/is-Diazido-tetra- kis(pyrazole)nickel(II) and rra/is-Diazido-tetrakis(3-methylpyrazoIe)nickel(II)  
 Abstract    The molecular nickel complexes fra«s-diazido-tetrakis(pyrazole)nickel(II) and trans-dia-zido-tetrakis(3-methylpyrazole)nickel(II) feature terminal monohapto-bound azide ligands. The pyrazole (pyr) ring planes are aligned along the Nazide-Ni-Nazide axis by intramolecular N-H—Nazide bonds. The crystal packing is controlled by jr-stacking between both pyrazole rings and azide ligands, N -H —Nazide hydrogen bonds, and intermolecular N-H—jrpyr and C-H —N/jrazide interactions. 
  Reference    Z. Naturforsch. 56b, 1205—1208 (2001); received July 20 2001 
  Published    2001 
  Keywords    Nickel Complexes, ^-Stacking, Hydrogen Bonding 
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 TEI-XML for    default:Reihe_B/56/ZNB-2001-56b-1205.pdf 
 Identifier    ZNB-2001-56b-1205 
 Volume    56