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Facet section ZfN Section B:Volume 051 [X]

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81	Author	O. Schrandt, Hk Müller-Buschbaum	Requires cookie*
	Title	K + auf einer mit C a2+ unterbesetzten Punktlage in Ca3( V 0 4) 2: Ein Beitrag über K C a 10V 7O 28 K + at an D eficient Ca2+ Point Position in C a3( V 0 4) 2: On K C a 10V 7O 28
	Abstract	Single crystals o f K C a ^ V y O ,« have been prepared by crystallization from flux. The yellow-green crystals show rhombohedral symmetry (trigonal space group C3V-R3c, a = 10.830(1), c = 37.860(1) A , Z = 6). The differences o f the crystal chemistry are discussed with respect to the isotypic compound Ca3(V 0 4) 2. K + replaces exclusively Ca2+ ions at one deficient point position.
	Reference	Z. Naturforsch. 51b, 473—476 (1996); eingegangen am 16. Oktober 1995
	Published	1996
	Keywords	Potassium, Calcium, Vanadium Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0473.pdf
	Identifier	ZNB-1996-51b-0473
	Volume	51

82	Author	O. Schrandt, Hk Müller-Buschbaum	Requires cookie*
	Title	Geordnete Metallverteilung in K B a V 0 4 und K S rV 0 4 mit /?-K2S 0 4-Struktur Ordered Metal Distribution in K B a V 0 4 and K S r V 0 4 Showing p -K 2S 0 4 Structure
	Abstract	Single crystals of K B a V 0 4 (I) and K S rV 0 4 (I I) have been prepared by crystallization from V 20 5 flux. The yellowish crystals show orthorhombic symmetry, space group D'^-Pnma with (I): a = 7.774(2), b = 5.899(1), c = 10.375(2) A , (II): a = 7.400(2), b = 5.812(1), c -9.961(1), Z = 4. Both compounds show an ordered distribution o f K + and Ba2+ and Sr2+ respectively. The different sizes of the K 0 1() and BaOy (S r 0 9) polyhedra are discussed with respect to those of the /3-K2S 0 4 structure, considering the calculations o f the Coulomb terms of lattice energy.
	Reference	Z. Naturforsch. 51b, 477—480 (1996); eingegangen am 5. September 1995
	Published	1996
	Keywords	Potassium, Strontium Barium, Vanadium Oxid, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0477.pdf
	Identifier	ZNB-1996-51b-0477
	Volume	51

83	Author	E. Peters, Hk Müller-Buschbaum	Requires cookie*
	Title	Mit Bor besetzte kondensierte Cluster in Ta5G e3B y (y ~ 0,7)
	Abstract	Tantalum, Germanium, Cluster Bronze coloured, rod-shaped crystals o f Ta5G e3By have been prepared by C 0 2-LA S E R -techniques. X-ray-methods confirm the well known hexagonal Mn5Si3 type, space-group D}sh-P 6 3/mcm, a = 7.6276(6) and c = 5.2781(9) A . The Ta6-clusters are centred by boron atoms.
	Reference	Z. Naturforsch. 51b, 481—484 (1996); eingegangen am 5. September 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0481
	Volume	51

84	Author	S. Frenzen, Hk Müller-Buschbaum	Requires cookie*
	Title	Eine silberhaltige Phase eines Oxoruthenats: A g (MN a2,3Ca4,3R u 0 8 A Silver Containing Phase o f an Oxoruthenate: A g 04N a 23Ca43R u O 8
	Abstract	Single crystals of A g 04Na23Ca43RuO8 have been prepared by heating Na20 2, CaO and ruthenium in closed silver tubes. Silver took part in the reaction. The crystal structure was investigated by X-ray techniques. A g 04N a2.3Ca43R uO 8 crystallizes with orthorhombic sym metry, space group D^-Cm m m ; a = 9.255(1), b = 6.683(1), c = 6.696(3) Ä , Z = 2. It shows relations to the sodium chloride structure. A statistical distribution of A g + and N a+ can be separated in micro space by splitting one oxygen position to give a dumb-bell like O -A g -O and an octahedral N a 0 6 coordination.
	Reference	Z. Naturforsch. 51b, 485—488 (1996); eingegangen am 16. Oktober 1995
	Published	1996
	Keywords	Silver, Sodium, Calcium, Ruthenium Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0485.pdf
	Identifier	ZNB-1996-51b-0485
	Volume	51

85	Author	J. Feldmann, Hk Müller-Buschbaum	Requires cookie*
	Title	Kristallstrukturuntersuchung am Barium-Yanadyl-Vanadat: Ba2(V 0)V 20 8 Crystal Structure Investigation of the Barium Vanadyl-Vanadate: Ba2(V 0 )V 20 8
	Abstract	Single crystals of Ba2(V 0)V 20 8 have been prepared by solid state reactions of Ba2V 20 7, V 9O 1 and V ^ 05 in sealed silica tubes. This compound crystallizes with monoclinic symmetry, space group C 1 -P 2 ,, a = 8.1174(9), b = 5.9699(9), c = 9.2903(9) A , ß = 113.94(1)°, Z = 2. V 5+ shows tetrahedral coordination. V 4+ inside ^ [V (3)0 4] chains is characterized by a square pyramidal coordination with a short apical V-O distance of 1.6 A typically for vanadyl groups. Ba2(V 0)V 20 8 represents a new structure type and is not isotypic to Sr2(V 0)V 20 8.
	Reference	Z. Naturforsch. 51b, 489—4 (1996); eingegangen am 22. August 1995
	Published	1996
	Keywords	Barium, Vanadium, Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0489.pdf
	Identifier	ZNB-1996-51b-0489
	Volume	51

86	Author	S. Münchau, Hk Müller-Buschbaum	Requires cookie*
	Title	Zur Kenntnis des ersten Alkalimetall-Cadmium-Halogeno-Oxovanadats: K4CdV50 15Cl On the First Alkaline-Cadmium-Vanadium Oxide Halide: K4CdV50 15Cl Crystal Structure, Alkaline-Cadmium-Vanadium Oxide Halide
	Abstract	Single crystals of K4CdV50 15Cl have been prepared by crystallization from melts. The yellow crystals show tetragonal symmetry, space group C4-P4, a = 9.097(1), c = 5.331(2) Ä, Z = 1. K4CdV50 ]5Cl belongs to the K4C uV5O i3Cl type. V (l) forms V 20 7 double tetrahedra connected by square V (2)O s pyramids and C d 0 4Cl2 octahedra. The crystal structure is dis cussed with respect to the isotypic compound K4CuV50 15Cl considering a short V (2)-0 di stance indicative of a vanadinyl group.
	Reference	Z. Naturforsch. 51b, 493—4 (1996); eingegangen am 7. Juni 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0493
	Volume	51

87	Author	Hans-JR. Akebrandta, Uwe Klingebiel, Mathias Noltem, Zdirad Zakb	Requires cookie*
	Title	]nonane -Syntheses und Crystal Structure
	Abstract	ferf-butyl-3.7-dichlor-2.4.6.8.9-pentaaza-1.3.5.7-tetrasilabicyclo[3.3.1.]nonan -Synthese und Kristallstruktur 1.3.5.7-Tetra-rm-butyl-3.7-dichloro-2.4.6.8.9-pentaaza-l.3.5.7-tetrasilabicyclo[3.3.1. Tetrasilabicyclo[3.3.1.]nonane, Silicon. Cyclosilazane The reaction of tert-butyltrichlorosilane with an excess of ammonia leads to the formation of a tetrasilabicyclo[3.3.1.]nonane, an NH-bridged cyclotetrasilazane. The crystal structure of the compound (M e3CSi)4Cl2(N H)5 is described.
	Reference	Z. Naturforsch. 51b, 498 (1996); eingegangen am 1. September 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0498
	Volume	51

88	Author	Wolfgang Weigand, Michael Weishäupl3, Christian Roblb	Requires cookie*
	Title	Metallkomplexe mit funktionalisierten Schwefelliganden, X [1] Ruthenium(II)-und Platin(II)-l-alkin-l-thiolato-Komplexe. Kristallstrukturanalyse von fr0/is-(Ph3P)2Pt[S-C=C-C(CH3)3]2 M etal Complexes of Functionalized Sulfur Containing Ligands, X [1] Synthesis of Ruthenium (II) and Platinum(II) 1-Alkyne-l-thiolato Complexes. X-Ray Structure Analysis of rra n s ^ P t^ P ^ P tfS -C ^ C -Q C H ^ k 1-A lkyne-l-thiolato Ligands, Platinum Complexes, Ruthenium Complexes, 31P CP/M AS N M R Spectra
	Abstract	The 1-alkyne-l-thiolates R -C =C -SLi [la: R = C(CH3)3, lb: R = C6H n ] react with L2PtCl2 (L = PPh3, 1/2 dppe) and CpRu(PPh3)2Cl, respectively to give the com plexes trans-(Ph3P)2Pt[S-C =C -C (C H 3)3]2 (2a), cis-dppePt[S-C=C-C(CH3)3]2 (2b), and CpRu(PPh3)2-(S -C = C -R) [3a: R = C(CH3)3, 3b: R = C6H U]. 2a has been characterized by 31P CP/M AS NM R spectroscopy and its crystal structure determined by X-ray diffraction.
	Reference	Z. Naturforsch. 51b, 501 (1996); eingegangen am 4. September 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0501
	Volume	51

89	Author	Fausto Calderazzoa, GiuseppeE. De, B. Enedettoa+, Ulli Englertb, Isabella Ferri3, Guido Pam, TrixieW. Agnerb	Requires cookie*
	Title	New Preparative Methods for the Halides of Titanium(II) and Vanadium(II): Reduction of Titanium(IV) Halides with Sodium and Oxidation of Bis(mesitylene)vanadium(0)
	Abstract	Titanium(II) Chloride. Vanadium(II) Chloride, Sodium Reduction TiCl4(T H F)2 reacts with two equivalents of sodium in THF to afford the soluble TiCl2(THF)" (1), which has been characterized analytically and by spectroscopic and m ag
	Reference	Z. Naturforsch. 51b, 506 (1996); received September 12. 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0506
	Volume	51

90	Author	DietrichK. Breitinger, Roman Breiter	Requires cookie*
	Title
	Abstract	?ram-(NH4)2[R u (S 0 3)2(N H 3)4]-4 H 20 (1) (m onoclinic, P l x!n\ a = 629.8(3), b = 1000.6(2), c = 1345.7(5) pm, ß = 112.25(4)°, Z = 2; R = 0.021; R w = 0.017) is obtained as pale greenish-yellow crystals by reaction of /ra « s-[R u (S 0 3H)2(N H 3)4] (2) with aqueous ammonia, and crys tallization at +5 °C. The compound, when isolated, is stable at room temperature for only a few days even under inert gas, but persists under the mother liquor. In the centrosymmetric anion frö/?s-[Ru(S03)2(N H 3)4]2~ the bonds Ru-S = 230.5(1) pm are significantly longer than in the neutral complex 2 (227.6(1) pm), whereas the Ru-N bonds are the same in both com plexes within experimental error (averages 214.1 and 214.0 pm). Hence, the mutual trans-influence of the sulfite ligands is weakened on protonation; the bonding of the co-ligands in c/s-position is not affected. The internal structure o f the sulfite ligand in 1 with long S-O bonds (average 151.2(5) pm) and small angles O-S-O (average 106.1(6)°) and the weakened Ru-S bond are a good match. The structure of 1 is held together by a complex network of hydrogen bonds, in which all potential hydrogen-bond donors (O H 2, N H 4+, N H 3) and accep tors (H 20 , S 0 3) are involved. The structural findings are reflected in the vibrational spectra.
	Reference	Z. Naturforsch. 51b, 517 (1996); received August 25 1995
	Published	1996
	Keywords	Ruthenium(II) Sulfito Complex, Crystal Structure, m ws-Influence, Hydrogen Bonding
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	Identifier	ZNB-1996-51b-0517
	Volume	51

91	Author	Lithiumteilstruktur Von Lithiumnitridtribromid, Und Li6nbr3, Lithiumnitridtriiodid, Li6ni3, Rupert Marx3, Hans Michael, M. Ayerb	Requires cookie*
	Title	Darstellung und
	Abstract	Single phase Li6N Br3 was prepared by the reaction of Li3N and dry, OH-free LiBr at 450°C. It is the most bromide rich com pound in the quasi binary system Li3_2.vN 1_*Brv. The crystal structures o f Li6N Br3 and o f isotypic Li6NI3, have been redetermined from neutron powder diffraction data. Both compounds crystallize in the cubic space group Fm3m (No. 225), a(Li6N Br3) = 894.18(7), a(Li6N I3) = 951.7(1) pm with 4 formula units per unit cell. The anion sublattice comprises a rock salt like arrangement of N with one o f the three halogen atoms (H a ll), with the remaining halogen atoms in the resulting N4Hal4 cubes. The structure may be regarded as an ordered A X 3 variation of a body-centered packing. The lithium atoms are disordered over the 96 (distorted) tetrahedral N X 3 holes in such a way that of the four neighbouring, face-sharing NBr3 tetrahedra along an N -H all-connection line only one is occupied. The resulting Li coordination polyhedron around N (and H a ll) is a distorted octa hedron with 6 equidistant Li atoms. Hal2 is surrounded by 12 Li atoms. The Li6NHal3 struc ture may be regarded as an anti-form of the cryolite structure.
	Reference	Z. Naturforsch. 51b, 525 (1996); eingegangen am 17. Juli 1995
	Published	1996
	Keywords	Lithium Nitride Trihalogenide, Preparation, Crystal Structure
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	Identifier	ZNB-1996-51b-0525
	Volume	51

92	Author	Stefan Anfang3, Kurt Dehnicke3, Jörg Magullb	Requires cookie*
	Title	Die Kristallstrukturen der Dysprosium-Komplexe [DyCl3(DME)2] und [DyCl2(THF)5]+[DyCl4(THF)2] ~ Crystal Structures of the Dysprosium Complexes [DyCl3(D M E)2] and [DyCl2(TH F)5]+[DyCl4(TH F)2]
	Abstract	[D yCl3(D M E)2] (D M E = 1,2-dimethoxyethane) has ben prepared from the known tetrahy-drofuran complex [Dy2Cl6(TH F)7] in boiling DM E. Both com plexes were characterized by structure determinations. [D yCl3(D M E)2]: Space group P2j/c, Z = 4, lattice dimensions at -7 0 °C: a = 1141.9(6), b = 884.2(4), c = 1558.3(6) pm, ß = 104.83(4)°. The complex has a molecular structure with a distorted pentagonal bipyramidal geometry in which the oxygen atoms o f the chelating DM E m olecules and one chlorine atom occupy the pentagonal plane. [D yC l2(T H F)5]+[DyCl4(TH F)2]~: Space group C2/c, Z = 4, lattice dim ensions at -7 0 °C: a -1241.4(9), b = 1139.4(6), c = 2735.1(19) pm, ß = 91.19(4)°. The com plex contains a seven-coordinate cation with axial chloride ligands in a pentagonal bipyramidal structure and a six-coordinate anion with a trans octahedral geometry.
	Reference	Z. Naturforsch. 51b, 531 (1996); eingegangen am 26. Oktober 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0531
	Volume	51

93	Author	Thomas Dahlems, Dietrich Mootz, Michaela Schilling	Requires cookie*
	Title	Zweidimensionales Eis und H50 2+-Ionen. Zur Bildung und Struktur tiefschmelzender molekularer und ionischer Hemi-bis Hexahydrate halogenierter Essigsäuren CCl"F3."COOH (n = 1 bis 3) [1] Two-Dimensional Ice and H 50 2+ Ions. On Formation and Structure of Low-Melting Molecular and Ionic Hemi-through Hexahydrates of Haloacetic Acids CCl"F3."COOH (n = 1 to 3) [1]
	Abstract	Hydrate formation o f haloacetic acids CCl"F3_"COOH (n = 1, 2, 3) has been studied by D TA and tem perature-dependent X-ray powder diffraction, and evidence obtained for five phases, all melting at temperatures below ambient. The hydrates have been confirmed and further characterized by their crystal structures at -1 5 0 °C. Three lower hydrates, CC12F C O O H 0.5H -> 0 (space group P2,/c and Z = 8 formula unites per unit cell), CC1F2C 0 0 H H 20 (P2,/c, Z = 4), and CC1F2C 0 0 H -4 H 20 (P I, Z = 2), have molecular structures with the acid and water m olecules hydrogen-bonded in two-dimensional arrays. The structures of the remaining hydrates, CCl2F C O O H -6H 20 and CC13C 0 0 H -6 H 20 (sim i lar, but not isotypic, both P 1 and Z = 2), are ionic, as (H s0 2+)(C X 3C 0 Ö) -4 H 20 , and three-dimensional. The neutral water molecules are hydrogen-bonded in ice-like layers rare in crystal chemistry. A lso, CCl2FCOOH is established only as the second acid o f which a lower hydrate is molecular and a higher one ionic.
	Reference	Z. Naturforsch. 51b, 536 (1996); eingegangen am 16. Oktober 1995
	Published	1996
	Keywords	Crystal Structure, Haloacetic Acid Hydrate, Hydrogen Bonding, Melting Diagram
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	Identifier	ZNB-1996-51b-0536
	Volume	51

94	Author	W. Lübbe, W. Preetz	Requires cookie*
	Title	Darstellung, n B-, 13C-, !H-NMR-und Schwingungsspektren von //-Methylen-bis
	Abstract	hexahydro-c/öso-hexaborat, [B6H6(CH2)B6H6]2_, und Kristallstruktur von [As(C6H5)4]2[B6H6(CH2)B6H6]* V2(CH3)2CO Preparation, "B , 13C, NM R and Vibrational Spectra of //-M ethylene-bis-hexahydro-doso-hexaborate, [B6H 6(C H 2)B6H 6]2~, and Crystal Structure of [As(C6H 5)4]2[B6H 6(C H 2)B6H 6] • V2 (CH3)2CO ^-M ethylene-bis-hexahydro-c/oso-hexaborate(2-), '
	Reference	Z. Naturforsch. 51b, 545 (1996); eingegangen am 19. Septem ber 1995
	Published	1996
	Keywords	H NM R Spectra, Vibrational Spectra, 13C NMR Spectra, n B NMR Spectra
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	Identifier	ZNB-1996-51b-0545
	Volume	51

95	Author	W. Preetz, B. Steuer	Requires cookie*
	Title	Darstellung, Schwingungsspektren und Normalkoordinatenanalyse der 10B-und n B-Isotopomeren von [B2(NCS)6]2_ sowie Kristallstruktur von (Ph3P=N=PPh3)2[B2(NCS)6]
	Abstract	By reaction of [B6H 6]2_ with a solution of (SCN)2 in dichloromethane in the presence of solid KOH the hexaisothiocyanatodiborate anion [B2(NCS)6]2~ is formed and can be isolated by fractionated crystallization. The crystal structure of (PNP)2[B2(NCS)6] has been determ i
	Reference	Z. Naturforsch. 51b, 551—556 (1996); eingegangen am 11. August 1995
	Published	1996
	Keywords	H exaisothiocyanatodiborate(2-), Crystal Structure, Vibrational Spectra, Isotopomers, Normal Coordinate Analysis
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	Identifier	ZNB-1996-51b-0551
	Volume	51

96	Author	Rolf Minkwitz, Jens Jakob, Andreas Kornath, Hans Preut	Requires cookie*
	Title	Uber die Darstellung, spektroskopische Charakterisierung und Kristallstruktur von Trifluormethylazosulfbn-N,N-dimethylamid (CH3)2N S (0)2NNCF3 On the Preparation, Spectroscopic Characterization and Crystal Structure of Trifluoromethylazosulfon-N,N-dimethylamid (C H 3)2N S (0 )2NNCF3
	Abstract	The reaction of Trifluoronitrosomethan with (CH3)2NS(0)2N H 2 in T H F and Na2C 0 3 as
	Reference	Z. Naturforsch. 51b, 557—562 (1996); eingegangen am 10. O ktober 1995
	Published	1996
	Keywords	Trifluormethylazosulfon-N, N-dimethylamid, Vibrational Spectra, NM R Spectra, Mass Spectra, Crystal Structure
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	Identifier	ZNB-1996-51b-0557
	Volume	51

97	Author	Heide Kraudelt, Eberhard Ludwig, Uwe Schilde, E.Rhard Uhlemann	Requires cookie*
	Title	Hydrolyse von Trifluoracetylaceton-salicylhydrazon. Struktur von Aceton-salicylhydrazon Hydrolysis of Trifluoroacetylacetone Salicylhydrazone. Structure of Acetone Salicylhydrazone
	Abstract	The reaction of trifluoroacetylacetone with salicylhydrazone gives acetone salicylhydra zone besides the expected trifluoroacetylacetone salicylhydrazone. The resulting mixture was analyzed by mass spectroscopy. The structure of acetone salicylhydrazone was determined by X-ray analysis. Crystal data: a = 12,8493(12) A, b = 6,1084(8) A, 4; R = 0,051; 750 unique reflexions.
	Reference	Z. Naturforsch. 51b, 563—566 (1996); eingegangen am 15. August 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0563
	Volume	51

98	Author	G. O. Stendorp3, O. Tterb, H. Hom	Requires cookie*
	Title	Syntheses and Properties of Cerium Diphthalocyanines in High Oxidation States; Crystal Structure of [C e(Pc)2](BF4) 0.33
	Abstract	Ring oxidized green Cerium(IV)diphthalocyanines, [Ce(Pc)2]X (X = (poly)halide, N 0 3_) are prepared by chemical oxidation of ("Bu4N)[Ce(Pc2~)2] with the corresponding halogen in solution or of solid [Ce(Pc2_)2] with aqueous HNO> Electrochemical oxidation of ("Bu4N)[Ce(Pc2_)2] in solution in the presence of ("Bu4N)BF4 yields [Ce(Pc)2](BF4)0.;p, which crystallizes in the tetragonal space group P4/nnc (a, b = 19.643(3) A, c = 6.525(3) A, Z = 2). The CeIV ion is eightfold coordinated by the isoindole N atoms (Niso) of the two staggered (ca. 41°), slightly distorted Pc ligands. The "[Ce(Pc)2]<)33+" subunits are arranged in infinite columns along [001] with the Ce atoms statistically disordered over two positions and C e -N iso bond lengths of 2.45(1) and 2.69(1) A, respectively The UV-VIS spectrum is dominated by the transitions of the Pc2-ligand at ca. 15,000 (B band), 30,000 and 36,000 cm -1 (Q, N region). A low energy ("metallic") band at ca. 2800 cm -1 typical for partially oxidized systems is present. The UV-VIS-NIR spectrum of [Ce(Pc)2]N 0 3 indicates a cofacial Pc2" -P c -complex. In addition to the jt-jz' transitions of the Pc2-moiety at ca. 14,000, 30,000 and 36,000 cm-1, the Ch transition of the Pc-ring is observed at ca. 19,200 cm -1 and the typical N IR band at 6380 cm -1. Oxidation of a thin film of (PNP)[Ce(Pc2_)2] with dry Br2/ N2 gas yields purple [Ce(Pc_)2]B rv, whose UV-VIS-NIR spectrum shows the diagnostic fea tures of dimeric Pc~ radicals with intense bands at ca. 14,000 and 18,000 cm -1 assigned as B and Qi bands, respectively. A t ca. 9000 cm 1 the typical Q D absorption is observed. The vibrational spectra are dom inated by the transitions of the Pc-ligand at 1305/1445 cm -1 (IR) and 560/1120/1172/1591 cm-1 (resonance Raman). Excitation with 1064 nm strongly enhances the sym. C e -N stretch at 163 c m '1.
	Reference	Z. Naturforsch. 51b, 567—573 (1996); received September 14 1995
	Published	1996
	Keywords	Diphthalocyanines, Cerium Compounds, Crystal Structure, UV-VIS-NIR Spectra, Vibrational Spectra
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	Identifier	ZNB-1996-51b-0567
	Volume	51

99	Author	Rostislav Lam, H. Erbert Wanjekb, Wolfgang Beckb	Requires cookie*
	Title	Metallkomplexe mit biologisch wichtigen Liganden, LXXXIII [1]. Palladium(II)-und Platin(II)-Komplexe mit 2-Hydroxyiminocarboxylaten und ihren Derivaten Metal Complexes of Biologically Im portant Ligands, LXXXIII [1], Palladium(II) and Platinum (II) Complexes of 2-Hydroxyiminocarboxylates and their Derivatives
	Abstract	Palladium(II), Platinum(II), 2-Hydroxyiminocarboxylate, Oximes of Pyruvoyl a-A m ino Acids The synthesis and spectroscopic properties of palladium(II) and platinum (II) chelate com plexes with carboxylates of 2-hydroxyiminopropionic, 2-hydroxyimino-3-phenylpropionic acids, with the amide and N-methylamide of 2-hydroxyiminopropionic acid, and with oximes of pyruvoylglycine and pyruvoyl-L-phenylalanine are reported.
	Reference	Z. Naturforsch. 51b, 574—580 (1996); eingegangen am 17. Juli 1995
	Published	1996
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	Identifier	ZNB-1996-51b-0574
	Volume	51

100	Author	Rostislav Lam, ShahramM. Ihanb, Wolfgang Beckb	Requires cookie*
	Title	Metallkomplexe mit biologisch wichtigen Liganden, LXXXY [1] Koordinationsverbindungen von Cobalt(III), Iridium(III), Ruthenium(II) und Palladium(II) mit Isoxazol-und Isoxazolin-3-carboxylaten M etal Complexes of Biologically Im portant Ligands, LXXXV [1] Coordination Compounds of C obalt(III), Iridium (III), R uthenium (II) and Palladium(II) with Isoxazole-and Isoxazoline-3-carboxylates
	Abstract	Chelate complexes of 5-phenyl-isoxazole-3-carboxylate (L 1) and 5-phenyl-isoxazoline-3-carboxylate (L2) ligands were prepared: PdfL 1)-). C p(C l)Ir(L '), (p-cym ene)(Cl)Ru(L1), Pd(L2)2, (Et3P)(Cl)Pd(L2), C6H4CH 2N M e2Pd(L2)-L 2H, Cp(I)Co(L2), Cp(Cl)Ir(L2) (10), and (p-cymene)(Cl)Ru(L2) (Cp = C5Me5). The structure of 10 was determined by X-ray diffraction.
	Reference	Z. Naturforsch. 51b, 581—587 (1996); eingegangen am 27. Juli 1995
	Published	1996
	Keywords	Isoxazole-3-carboxylate, Isoxazoline-3-carboxylate, Chelate Complexes, Cobalt, Iridium
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	Identifier	ZNB-1996-51b-0581
	Volume	51

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