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Facet section ZfN Section B:Volume 051 [X]

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1

1	Author	Ute Berger, Wolfgang Schnick	Requires cookie*
	Title	Ba2Na(CN2)(CN)3, ein neues Cyanamid-cyanid mit interpenetrierenden Teilstrukturen Ba2Na(CN2)(CN)3, a Novel Cyanamide Cyanide with Interpenetrating Substructures
	Abstract	Ba2Na(CN2)(CN)3 was obtained by the reaction of Ba2N with melamine and NaCN at 700 °C. The compound was structurally characterized by single-crystal X-ray investigations (Fd3m, a = 1518.8(3) pm, Z = 16). In the crystal structure the Ba"+ ions form a cubic close packed arrangement, the Na+ and the CN2_ ions occupy the octahedral interstices. The CN-ions are located within the close packed Ba2+ layers. The unit cell of Ba2Na(CN2)(CN)3 contains two interpenetrating substructures of the zinc-blende structure type, building up a variant of NaTl. A reversible phase transition has been observed during cooling of the compound. Whereas the Ba2(CN2)(CN)3 sublattice remains nearly unaffected in this process, the Na+ ions of the low-temperature phase are statistically distributed on two crystallographic positions.
	Reference	(Z. Naturforsch. 51b, 1—8 [1996]; eingegangen am 7. Juni 1995)
	Published	1996
	Keywords	Cyanamide Cyanides, Synthesis, Crystal Structure, Vibrational Spectra
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0001.pdf
	Identifier	ZNB-1996-51b-0001
	Volume	51

2	Author	Michael Feist, Sergej Trojanov, Erhard Kemnitz	Requires cookie*
	Title	Die Kristallstrukturen von 1,4-Dimethylpiperazinium-tetrabromo- cobaltat(II) und -zinkat(II), (dmpipzH2) [Mn Br4] (M = Co, Zn)
	Abstract	The Crystal Structures of 1,4-Dimethylpiperazinium Tetrabromocobaltate(II) and -Zincate(II), (dmpipzH2) [MHBr4] (M = Co, Zn) The compounds (dmpipzH2)[MnBr4] (M = Co, Zn) crystallize at room temperature from equi-molar solutions of 1,4-dimethylpiperazine and MBr2 • n H20 in 3M HBr. (dmpipzH2)[CoBr4] is isotypic with the homologous chlorometalates of Co and Zn and crystallizes in the mono clinic space group P2,/m with a = 6.424(3), b = 14.588(6), c = 7.102(6) A, ß = 90.87(6)°, Z = 2. (dmpipzH2)[ZnBr4], however, crystallizes in the monoclinic space group P2,/c with a = 7,605(5), b = 13,760(9), c = 13,286(7) Ä, ß = 93,03(6)°, Z = 4. Both structures con tain centrosymmetric cations (dmpipzH2)2+ in the chair form and slightly distorted tetrahedra [MBr4]2~ with a mirror plane in the case ofM = Co. Several distances N- • -Brin both structures are interpreted in terms of N-H- • Br hydrogen bonds which are favoured by the packing in the case of M = Zn.
	Reference	(Z. Naturforsch. 51b, 9—13 [1996]; eingegangen am 12. Juni 1995)
	Published	1996
	Keywords	1, 4-Dimethylpiperazinium Tetrabromometalates(II), Cobalt, Zinc, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0009.pdf
	Identifier	ZNB-1996-51b-0009
	Volume	51

3	Author	E. Kemnitz3, C. Werner3, A. Stiewe3, H. Worzalab, S. Trojanov3	Requires cookie*
	Title	Synthese und Struktur von Zn(HS0 4)2(H2S0 4)2 und Cd(H S04)2 Synthesis and Structure of Z n(H S04)2(H2S 0 4)2 and C d(H S 04)2
	Abstract	From the binary systems M2S 0 4/H2S 0 4 (M = Zn, Cd), two new hydrogen sulfates, (Zn(HS0 4)2(H2S04)2 and Cd(HS04)2, have been synthesized and structurally characteri zed. Both compounds crystallize in the monoclinic space group P2,/c with cell parameters a = 5.047(2), b = 15.430(4), c = 7.958(3) A and ß = 104.16(4)° (Z= 2) for Zn(HS04)2(H2S 0 4)2 and a = 5.339(1), b = 13.351(3), c = 8.508(2) A and ß = 92.22(3)° (Z = 4) for Cd(H S04)2. In the zinc compound there are slightly distorted centrosymmetric Z n 06 octahedra with Z n -0 distances of 2.05 -2.13 A which are sharing corners with S 0 4 tetrahedra. H S 04 and H2S 0 4 tetrahedra are linked via hydrogen bonds to form layers perpendicular to the c-axis. In the crystal structure of C d(HS04)2there exist two crystallographically different H S 04 tetrahedra. The C d06 octahedra with C d -0 distances between 2.24 and 2.31 A are strongly angle-distorted. Besides hydrogen bonds of medium strength (d0...o = 2.66 A) there are also much more weaker ones (d0...0 = 3.04 A). Considering these latter ones zigzag chains in z-direction can be recognized. The relatively low stability of Cd(H S04)2 in comparison with other metal-II-hydrogen sulfates is discussed with respect to its structural pecularities.
	Reference	(Z. Naturforsch. 51b, 14—18 [1996]; eingegangen am 13. Juni 1995)
	Published	1996
	Keywords	Synthesis, Crystal Structure Zinc, Cadmium, Hydrogen Sulfate
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0014.pdf
	Identifier	ZNB-1996-51b-0014
	Volume	51

4	Author	S. Trojanov, A. Stiewe, E. Kemnitz	Requires cookie*
	Title	Synthese und Struktur saurer Ubergangsmetallsulfate - Ti(H50 2)(S 0 4)2(H20 ) 2 und Zr(H30 ) 2(S 0 4)3 Synthesis and Structure of Acid Transition Metal Sulfates - Ti(H50 2)(S 0 4)2(H20 )2 and Zr(H30 ) 2(S 0 4)3
	Abstract	From the ternary system Mn(S 0 4)n/2 / S 0 3 / H20 (Mn+ = Zr4+, Ti3+) two new acid metal sulfates, Ti(H50 2)(S 0 4)2(H20)2 and Zr(H30) 2(S 0 4)3, have been synthesized and structurally characterized. Ti(H50 2)(S 0 4)2(H->0)i crystallizes in the orthorhombic space group Pnma with cell parameters a = 9.858(5), b = 18.32(2), c = 5.437(7)Ä (Z = 4); Zr(H30) 2(S 0 4)3 crystallizes in the triclinic space group PI with cell parameters a = 5.092(2), b = 8.533(3), c = 12.388(6)A, a = 92.95(3)°, ß = 90.89(3)°, 7 = 94.35(3)° (Z= 2). In the titanium compound there are slightly distorted T i0 6 octahedra with T i-0 distances between 1.99 and 2.09 A which are sharing corners with S 0 4 tetrahedra. Through hydrogen bonds layers are formed perpendicular to the 6-axis. These layers are connected by H30 + ions only. The structure of Zr(H30) 2(S 0 4)3 consists of three different S 0 4 tetrahedra and distorted Zr07 polyhedra which are connected via common corners and edges to form columns parallel to the a-axis. The Z r-0 distances vary from 2.13o to 2.18A for equatorial positions, significantly longer than the axial Zr-O distances with 2.05A.
	Reference	(Z. Naturforsch. 51b, 19—24 [1996]; eingegangen am 13. Juni 1995)
	Published	1996
	Keywords	Synthesis, Crystal Structure, Titanium, Zirconium, Hydrogen Sulfates
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0019.pdf
	Identifier	ZNB-1996-51b-0019
	Volume	51

5	Author	D. Frerichs, Hk Müller-Buschbaum	Requires cookie*
	Title	Vier verschiedene Koordinationspolyeder um Cu2+ im Oxid-Arsenat-Phosphat Cu0
	Abstract	(Cu,M g)3(As1_xPJt:0 4)2 (x = 0,3) Four Different Coordination Polyhedra Around Copper in the Oxide-Arsenate-Phosphate C u0(C u,M g)3(A s,_xP,.04)2 (x = 0.3) Single crystals of CuO(Cu,Mg)3[(As0.7P0.3)O4]2 have been prepared by crystallization from melts. The compound crystallizes with triclinic symmetry, space group C '-P l, a = 6.372(4), b = 7.643(7), c = 8.175(5) A, a = 98.59(6), ß = 112.26(3), 7 = 99.03(3)°, Z = 2. CuO(Cu,Mg)3[(Aso)7Po 3)0 4]2 is isotypic to Cu4(P 0 4)20 . X-ray investigations show square planar C u 04 polygons, twisted tetragonal C u 0 5 pyramids, C u 05 bipyramids and elongated (Cu,M g)06 octahedra.
	Reference	(Z. Naturforsch. 51b, 25—28 [1996]; eingegangen am 27. Juli 1995)
	Published	1996
	Keywords	Copper, Magnesium, Arsenate, Phosphate, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0025.pdf
	Identifier	ZNB-1996-51b-0025
	Volume	51

6	Author	E. Peters, Hk Müller-Buschbaum	Requires cookie*
	Title	Über ein niedervalentes Titan-Wolframoxid: Ti0 ,54W 0,46^2 On a Low Valent Titanium Tungsten Oxide: Ti0 54W 0 .46^2
	Abstract	Single crystals of Ti0 .54W0. 460 2 have been prepared by C 0 2-LASER techniques. This phase crystallizes with a non-distorted rutile structure, space group D4h-P42/mnm, a = 4.6862(4), c = 2.9039(3) A, Z = 2. Split positions of the statistically distributed metal ions show the existence of W-W pair formation as reported for pure W 0 2.
	Reference	(Z. Naturforsch. 51b, 29—31 [1996]; eingegangen am 27. Juli 1995)
	Published	1996
	Keywords	Titanium, Tungsten-Pairs, Rutile-Type
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0029.pdf
	Identifier	ZNB-1996-51b-0029
	Volume	51

7	Author	Michael Wachhold, WilliamS. Sheldrick	Requires cookie*
	Title	Methanolothermale Synthese und Kristallstruktur von Tetraselenidoar- senaten(V) und -antimonaten(V) des Rubidiums und Cäsiums Methanolothermal Synthesis and Crystal Structure of Tetraselenidoarsenates(V) and -antimonates(V) of Rubidium and Cesium
	Abstract	Tetraselenidoarsenates(V) and -antimonates(V), Rubidium, Cesium, Methanolothermal Synthesis, Crystal Structure Methanolothermal reaction of M2C 0 3 (M = Rb, Cs) with E2Se3 (E = As, Sb) and Se at temperatures in the range 180 -200°C leads to the formation of tetraselenidoarsenates(V) and -antimonates(V) M3ESe4 in moderate to quantitative yields. All four compounds crystallize in the (NH4)3AsS4 structure type (space group Pnma) and contain isolated slightly distorted tetrahedral ESe4~ anions with crystallographic Cs symmetry. Both of the independent cations are coordinated in an irregular manner by seven Se atoms.
	Reference	(Z. Naturforsch. 51b, 32—36 [1996]; eingegangen am 28. Juni 1995)
	Published	1996
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0032.pdf
	Identifier	ZNB-1996-51b-0032
	Volume	51

8	Author	AnnemarieL. Wessels, Wolfgang Jeitschko	Requires cookie*
	Title	Preparation and Crystal Structure of the Mercury(I) DimoIybdate(VI) Hg2Mo20 7
	Abstract	Crystal Structure, Magnetic Susceptibility, Mercury Molybdates(VI) Yellow, flat, needle-shaped, diamagnetic crystals of Hg2Mo20 7 were obtained by decompo sition of Hg2M o 0 4 in evacuated, sealed silica tubes at 550 °C. Their crystal structure was determined from four-circle diffractometer data: P I, a = 709.7(2), b -714.4(2), c = 803.8(2) pm, a = 64.89(1)°, ß -66.09(1)°, y = 66.45(1)°, Z = 2, R = 0.030 for 3165 structure factors and 66 variables. The molybdenum atoms are coordinated by four oxygen atoms at 171 to 195 pm in a very distorted tetrahedral arrangement. These tetrahedra are linked via a com mon oxygen atom, thus forming Mo20 7 groups. The tetrahedral oxygen coordination of each molybdenum atom is augmented by two additional oxygen atoms at 218 to 231 pm, which leads to a distorted octahedral coordination for the molybdenum atoms. These M o 0 6 octa-hedra are connected via common corners and edges and in this way they form two-dimen-sionally infinite sheets, which are separated by the
	Reference	(Z. Naturforsch. 51b, 37—41 [1996]; received May 22 1995)
	Published	1996
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0037.pdf
	Identifier	ZNB-1996-51b-0037
	Volume	51

9	Author	Dagm Ar, Henschel Arm, Blaschette, PeterG. Jones	Requires cookie*
	Title	Polysulfonylamine, LXX [1] Das Assoziat EtOH *** OH2 als Bindeglied in einem quaternären 18-Krone-6-Neutralmolekül-Komplex: Bildung und Kristallstruktur von (CH2CH20 ) 6-2 H20 -2 EtOH -2 H N (S 02Ph)2
	Abstract	Di(benzenesulfonyl)amine, 18-Crown-6, Quaternary Complex of Uncharged Molecules, Crystal Structure Co-crystallization of 18-crown-6 (18 C 6) and di(benzenesulfonyl)amine from dry ethanol at -2 0 °C affords the thermally labile and structurally uncharacterized ternary complex 18C 6-2 EtOH-2 H N (S 0 2Ph)2 (2). Single crystals of the quaternary complex 18C6-2 H20 -2 E tO H -2 H N (S 0 2Ph)2 (1) were fortuitously obtained by repeated recrystallization of a sam ple of 2 from ethanol that was not kept completely dry. The crystal packing of 1 (triclinic, space group P I) is built up from isolated formula units displaying crystallographic inversion symmetry and pseudo D3d symmetry of the crown ring. The water molecules are located on opposite sides of the ring plane. Each H20 is connected to two Oc atoms of the crown separated by a [CH2CH2OCH2CH2] segment (OwH --O c 210 and 208 pm, angles at H 169 and 164°), and accepts an O -H —Ow hydrogen bond from an ethanol molecule (H —Ow 176 pm, angle 177°). The H N (S 0 2Ph)2 entities in turn are N-H-O bonded to the ethanol molecules (H —O 177 pm, angle 177°).
	Reference	(Z. Naturforsch. 51b, 42—46 [1996]; eingegangen am 7. Juni 1995)
	Published	1996
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0042.pdf
	Identifier	ZNB-1996-51b-0042
	Volume	51

10	Author	Sima Rabbani, Erwin Riedel	Requires cookie*
	Title	Verteilung und Valenz der Kationen im Spinellsystem ZnFeGa04-F e 2G a 0 4 Distribution and Valence of the Cations in the Spinel System Z n F eG a 0 4-F e 2G a 0 4
	Abstract	For the spinel system Zn1_A ;F e^ G a/l(Fe1+/lG a1_ /l)04 the index X has been determined by X-ray measurements: X = 0 in the region 0 < x < 0,35; the increase of X to 0,62 within 0,35 < x < 1 is nearly linear. The distribution of Fe2+ and Fe3+ ions over the lattice sites has been derived from lattice constants and ionic distances, and also by Mössbauer spectroscopy. In the spinels with x < 0,3 the tetrahedral sites are preferably occupied by Fe2+ ions, for x > 0,5 Fe3+ ions dominate. At x = 0,4 the occupation of the lattice sites by iron ions is statistical, the high temperature Mössbauer spectrum shows a single line only. All spinels are n-type hopping conductors mainly conducting via the octahedral sites.
	Reference	(Z. Naturforsch. 51b, 47—51 [1996]; eingegangen am 30. Juni 1995)
	Published	1996
	Keywords	Iron Gallium Spineis, Cation Distribution, Valence Distribution, Mössbauer Spectra, Seebeck Coefficients
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0047.pdf
	Identifier	ZNB-1996-51b-0047
	Volume	51

11	Author	A. Gordon, FrancisJ. Disalvo	Requires cookie*
	Title	R obert
	Abstract	The ternary compound Ce8Pd24Sb is very close in composition to the intermediate valent binary CePd3. A single crystal study yielded a cubic cell with a = 8.461 (1)A, Pm3m symmetry with wR2 = 0.0412 based on 1453 reflections (222 unique) and 16 parameters. This new structure type is composed of distorted perovskite and Cu3Au subcells arranged with the perovskite-like units centred on the corners of the cube. Fitting the magnetic susceptibility data above 100K to a Curie-Weiss expression yielded a Weiss constant of -15(3)K (anti ferromagnetic) and an effective high temperature moment per cerium of 2.45(4)/<B indicating trivalent cerium. No ordering was observed above 3K.
	Reference	(Z. Naturforsch. 51b, 52—5 [1996]; received May 17 1995)
	Published	1996
	Keywords	Cerium Intermetallic, Crystal Structure, Magnetic Susceptibility
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0052.pdf
	Identifier	ZNB-1996-51b-0052
	Volume	51

12	Author	M. Artin Hilbers, M. Argita Meiwald, R.Ainer Mattes	Requires cookie*
	Title	Mehrkernige Oxo-Vanadium-und Oxo-Molybdän
	Abstract	Komplexe mit dem Dianion der Quadratsäure als Brückenligand. Strukturen von [C(NH2)3]4[V202F4(C404)2]-4H20 , [-Bll4N]4[V303F4(C404)3]-2H20 , [Et4N]3[M0 3 0 8F(C40 4)2], [Et4N]4[Mo4O10F6(C4O4)] und [ E t 4N ] 3[ M o 20 3 C l3(C 40 4) 2] Polynuclear Complexes of Oxo-Vanadium and Oxo-Molybdenum with the Dianion of Squaric Acid as Bridging Ligand. Crystal Structures of [C(NH2)3]4[V20 2F4(C404)2]-4H20 , ["Bu4N]4[V303F4(C404)3]-2H20 , [Et4N]3[M0308F(C40 4)2], [Et4N]4[Mo4O 10F6(C4O4)] and [Et4N]3[Mo20 3Cl3(C40 4)2] Vanadium(IV), Molybdenum(V) and (VI), Oligonuclear Complexes Aqueous or methanolic solutions containing vanadium(IV), molybdenum(V) and molyb-denum(VI) oxo species and fluoride ions react with squaric acid to give the oligo nuclear complexes [C(NH2)3]4[V20 2F4(C40 4)2]-4H20 (1), Cs4[V30 3F4(C40 4)3]-5H20 (2a), ["Bu4N]4[V30 3F4(C40 4)3]-2H20 (2b), [Et4N]4[Mo4O 10F6(C4O4)] (3a), [Et4N]4[Mo4O 10Cl6(C4O4)] (3b), [Et4N]3[Mo30 8F(C40 4)2] (4) and [Et4N]3[Mo20 3Cl3(C40 4)2] (5). The structures of compounds 1, 2a, 2b, 3a, 4 and 5 have been determined by single crystal X-ray diffraction. The [V20 2F4(C40 4)2]4' ion in 1 consists of the planar V20 2F4 core with the vanadium sites bridged by two ,«-l,2-squarato ligands. The un ique cone-shaped [V303F4(C40 4)3]4" ion in 2a and 2b contains a central defect and severely distorted V 3F4 cubane unit. Each vanadium atom bears a terminal oxo ligand; pairs of vana dium atoms are bridged by ^-1,2-squarato ligands. The [Mo4O 10F6(C4O4)]4" ion in 3a consists of a squarate ion, which is coordinated to four metal centers. Pairs of metal atoms are bridged by 1 M(0)i «(F)-bridges. Two terminal oxo ligands and one terminal fluoro ligand complete the metal coordination. Oxo and fluoro ligands are partly disordered. The structure of the [Mo30 8F(C40 4)2]3' ion in 4 is related to the structure of [V303F4(C40 4)3]4\ It consists of a defect Mo3(0 3F) cubane unit. Two pairs of molybdenum atoms are bridged by ^-1,2-squarato ligands. Terminal oxo and dioxo groups complete the molybdenum coordination. The [Mo20 3Cl3(C40 4)2]3" ion in 5 exhibits a unique structure with a planar OClMo(w-0)(u-Cl)MoOCl core and a cis, ds-orientation of the oxygen ligands. Two ,«-1,2-squarato ligands bridge the molybdenum centers above and below the Mo20 3Cl3 plane.
	Reference	(Z. Naturforsch. 51b, 57 [1996]; eingegangen am 29. Mai 1995)
	Published	1996
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0057.pdf
	Identifier	ZNB-1996-51b-0057
	Volume	51

13	Author	Frederick Kurzer, Dennis Chapman	Requires cookie*
	Title	The Oxidation of Partially Acylated Myoinositols
	Abstract	1,3,4,6-Tetrakis-and 1,3,4,5,6-pentakis-acylmyoinositols are obtained by the controlled cat alyzed acylation of myoinositol. The extent of the substitution depends both on the reaction conditions and the structure o f the acylating agent, including steric factors. Chromic acid oxidation converts the acylmyoinositols into the corresponding 2-ketones. Under electron impact, the compounds undergo stepwise deacylation.
	Reference	(Z. Naturforsch. 51b, 68—7 [1996]; received May 17 1995)
	Published	1996
	Keywords	Tetrakisacylmyoinositols, Pentakisacylmyoinositols, Acylated M yoinososes-2, Mass Spectra, M yoinositol Esters
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0068.pdf
	Identifier	ZNB-1996-51b-0068
	Volume	51

14	Author	HkM. Üller-Buschbaum, B. M. Ertens	Requires cookie*
	Title	Single Crystal X-Ray Analysis of Ba3Ce R
	Abstract	Single crystals of (I) Ba3C eRu20 9, (II) Ba3SmRu20 9, (III) Ba3D yR u20 9, (IV) Ba3ErRu20 9 and (V) Ba3Ti24Ru0.6O 9 have been prepared by high temperature solid state reactions. The compounds were exam ined by X-ray techniques. They crystallize with hexagonal symmetry,
	Reference	(Z. Naturforsch. 51b, 79 [1996]; eingegangen am 18. Mai 1995)
	Published	1996
	Keywords	Barium, Rare Earth, Ruthenium Oxide, Titanium, Crystal Structure
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	Identifier	ZNB-1996-51b-0079
	Volume	51

15	Author	St Gallinat, Hk Müller-Buschbaum	Requires cookie*
	Title	Two Examples of Partial and Total Defects in the B a«Ln2Mo4O i6-Type: BaCu0 41 ■o,59Pr2Mo4 0 16 and BaBYb2Mo4Ojg
	Abstract	Single crystals of (I) BaCu0.4iPr2M o4O 16 and (II) BaYb2M o40 16 have been prepared by flux technique. Both compounds crystallize with m onoclinic symmetry, space group C2h-C 2 /c with (I): a = 5.352(11), b = 12.888(2), c = 19.399(4) A; ß = 90.89(3)°; (II): a = 5.181(7), b = 12.467(3), c -19.350(3) Ä , ß -91.93(2)°, Z = 4. The crystal structure is characterized by i [ B a M 0 12]-chains along [010]. In the first case the M positions are occupied by copper by about 41%, in the second case these positions remain com pletely unoccupied. With respect to the crystal chemistry of the reference compound Ba(Cu0.22Mg() 78)Nd2Mo4O 16 all substan ces of the composition BaLn2M o40 16 should be written as Ba»Ln2Mo40 16 indicating the holes in th e^ B a M O i^ -c h a in s by ■.
	Reference	(Z. Naturforsch. 51b, 85—8 [1996]; eingegangen am 7. Juni 1995)
	Published	1996
	Keywords	Barium, Copper, Rare Earth, Molybdenum Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0085.pdf
	Identifier	ZNB-1996-51b-0085
	Volume	51

16	Author	O. Sedello, Hk Müller-Buschbaum	Requires cookie*
	Title	Ein Oxometallat mit eindimensional flächenverknüpften Oktaederketten Synthesis and Crystal Structure of (C u,Fe)363M o3O i2. An Oxom etallate Showing One-Dimensional Chains of Face Sharing Octahedra
	Abstract	Single crystals of (C u ,F e)3-63M o30 12 have been prepared by crystallisation from melts. X-ray investigations lead to orthorhombic symmetry, space group D : 2-P 2 12121, a = 5.0952(8), b = 10.637(2), c = 17.881(3) A , Z = 4. (C u ,F e)363M o3O i2 is isotypic to Cu385M o30 12 or (C u,Z n)3 75M o30 12. M olybdenum shows tetrahedral coordination by oxygen. Cu+ and Fe2+ are probably distributed statistically over four different point positions. Interesting features of the crystal structure are one-dim ensional chains of face shared (C u ,F e)0 6 octahedra. S y n t h e s e u n d K r i s t a l l s t r u k t u r v o n (C u , F e) 3 ,63 M o 3 0 12.
	Reference	(Z. Naturforsch. 51b, 90—9 [1996]; eingegangen am 20. Juni 1995)
	Published	1996
	Keywords	Copper, Iron, M olybdenum, Oxide, Crystal Structure
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0090.pdf
	Identifier	ZNB-1996-51b-0090
	Volume	51

17	Author	Heide Kraudelt, Eberhard Ludwig, Uwe Schilde, E.Rhard Uhlemann	Requires cookie*
	Title	Molekülstrukturen von Tautomeren des Benzoylaceton-benzoylhydrazons Moleculare Structures of Tautomeric Forms of Benzoylacetone Benzoylhydrazone
	Abstract	Benzoylacetone Benzoylhydrazone, Pyrazoline Form, Enhydrazine Form By crystallization from benzene two tautomeric forms of benzoylacetone benzoylhydra zone were isolated side by side. They were found to be the pyrazoline(III) and the enhydrazi-ne(II) form. Crystal data: II: a = 9,247(2) Ä , b = 9,953(2) Ä , c = 16,112(4) A , a = 81,79(1)°, ß = 82,74(1)°, y = 89,94(2)°; space group P I; Z = 4; R = 0,0584; 6197 unique reflexions; III; a = 17,357(6) A, b = 21,190(7) A , c = 7,908(5) A; space group Pccn; Z -8; R = 0,0553; 1152 unique reflexions.
	Reference	(Z. Naturforsch. 51b, 95 [1996]; eingegangen am 29. Juni 1995)
	Published	1996
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	Identifier	ZNB-1996-51b-0095
	Volume	51

18	Author	Marianne Bäudler, Loert De, Riese-M Eyer	Requires cookie*
	Title	Beiträge zur Chemie des Phosphors, 238 [1] Synthese und Eigenschaften des Phosphinocyclotriphosphans (J-BuP)2P -P(SnMe3)2 Contributions to the Chemistry of Phosphorus, 238 [1] Synthesis and Properties of the Phosphinocyclotriphosphane (r-BuP)2P -P (S n M e3)2
	Abstract	[Bis(trimethylstannyl)phosphino]-di-tert-butylcyclotriphosphane, Triphosphacyclopropane, Triphosphirane, Inversion of Phosphorus
	Reference	(Z. Naturforsch. 51b, 101 [1996]; eingegangen am 16. Juni 1995)
	Published	1996
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0101.pdf
	Identifier	ZNB-1996-51b-0101
	Volume	51

19	Author	Anton Meller, Christoph Kümmel, Mathias Noltem	Requires cookie*
	Title	Monomere Iodide von o-substituierten Aryl-Gallium-und Indiumverbindungen Monomeric Iodides of o-Substituted Aryl Gallium and Indium Compounds
	Abstract	Monomerie diiodides of 2,4,6-tri(rm -butyl)phenyl = (s-M es), 2,4,6-triisopropylphenyl = (Trip)-and 2,4-di-terf-butyl-6-methylphenyl = (D BM P)-gallium and -indium were prepared by the reaction of the lithiated aryls with MI3 (M = Ga, In) in hexane/Et20 . s-M esInI2 (1), s-M es2InI (2), s-M esGaI2 (3), s-M es2GaI (4), Trip2InI (5) and (D B M P)2InI (6) were obtained and characterized by their mass and NM R spectra (!H, 13C), and/or by elem ental analyses. An X-ray crystal structure analysis was carried out for 1.
	Reference	(Z. Naturforsch. 51b, 107—111 [1996]; eingegangen am 6. Juni 1995)
	Published	1996
	Keywords	Galliumiodides, Indiumiodides, 2, 6-Disubstituted Aryl
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0107.pdf
	Identifier	ZNB-1996-51b-0107
	Volume	51

20	Author	Nickolia Lalioti3, JohnM. Tsangaris, ThF. Zafiropoulos, SpyrosP P Erlepes	Requires cookie*
	Title	Binding of Cations to 4 f Metal Ions : Preparation and Properties of Lanthanide(III) Complexes Containing the Phenelzinium(l+) Cation as a Ligand
	Abstract	Treatment o f Ln2(S 0 4)3 • nH 20 (Ln = La, Ce, Pr, Nd, Sm. Eu, Gd ; n -8, 9) with phenelzine dihydrogen sulfate, (phzH2) S 0 4, in 1 N H2S 0 4 yields polymeric complexes with the general formula [L n (S 0 4)2(H 20) 2(phzH)], which contain the phzH+ cation as a ligand. The compounds have been characterized by elem ental analyses, X-ray powder patterns, thermal methods, magnetic susceptibilities and spectroscopic (IR, Raman, electronic diffuse reflec tance and solid-state emission f -f spectra) studies. The prepared complexes most probably consist of 7-coordinated units, formed by four bridging bidentate sulfato groups, two terminal aqua m olecules and one cationic phzH+ ligand.
	Reference	(Z. Naturforsch. 51b, 112 [1996]; received May 19 1995)
	Published	1996
	Keywords	Lanthanide(III) Complexes, Phenelzine Dihydrogen Sulfate, Cationic Ligands, IR Spectra
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	TEI-XML for	default:Reihe_B/51/ZNB-1996-51b-0112.pdf
	Identifier	ZNB-1996-51b-0112
	Volume	51

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