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Facet   Publication Year 1987  [X]
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1987[X]
1Author    Michel Mégnamisi-Bélombé, Helmut EndresRequires cookie*
 Title    Two Modifications of Tetraethylammonium tranis-Diiodobis(ethanedialdioximato)cobaltate(III) with and without Intermolecular 1--I Interactions  
 Abstract    The structures of two modifications of [C 8 H 2 nN][C4H 6 Col2N 4 04], M r -617.11, have been deter-mined by X-rav investigations. Form 1 is orthorhombic, Pben, a = 8.417(2), b — 12.923(3), c = 18.444(3) A, V = 2006 Ä 3 , Z = 4, d c = 2.04 gem" 3 , final R w = 0.037 for 1989 reflections and 124 parameters. There are no unusual intermolecular interactions in this modification. From 2 is tetragonal, \A x md, a = 8.886(3), c = 25.841(6) Ä, V = 2040 Ä 3 , Z = 4, d c = 2.01 gem" 3 , final R w = 0.027 for 1629 reflections and 80 parameters. In this modification the metal complexes form strictly linear chains via short intermolecular I -I contacts, 3.722(1) Ä. 
  Reference    (Z. Naturforsch. 42b, 1—4 [1987]; received August 21 1986) 
  Published    1987 
  Keywords    Structure, Dioxime Complex, Iodine Interactions, Linear Chain Compounds 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0001.pdf 
 Identifier    ZNB-1987-42b-0001 
 Volume    42 
2Author    Helmut EndresRequires cookie*
 Title    Two Modifications of Di[tetra(methylthio)tetrathiafulvalenium] Hexachlorodicuprate(II), [(TTM-TTF) + ] 2 [CU 2 C1 6 ] 2 "  
  Reference    (Z. Naturforsch. 42b, 5—11 [1987]; received September 8 1986) 
  Published    1987 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0005.pdf 
 Identifier    ZNB-1987-42b-0005 
 Volume    42 
3Author    Manfred LisselRequires cookie*
 Title    Reaktionen mit Kaliumsuperoxid 3 [1] Über den Mechanismus der Ketonspaltung durch K0 2 Reactions with Potassium Superoxide 3 [1] On the Mechanism of the Cleavage of Ketones by K0 2  
 Abstract    Some experiments on the mechanism of the oxidative cleavage of ketones are presented. The results show that the general mechanism of base catalysed autoxidation is operating. 
  Reference    (Z. Naturforsch. 42b, 12—14 [1987]; eingegangen am 4. August/24. September 1986) 
  Published    1987 
  Keywords    Superoxide, Potassium Superoxide, Ketones 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0012.pdf 
 Identifier    ZNB-1987-42b-0012 
 Volume    42 
4Author    Vicente Fernández, Moisés Morán, JuanCarlos Doadrio, Elke Conradi, Wolfgang Willing, Ulrich MüllerRequires cookie*
 Title    EPR-Spektren von Tetrachlorocupraten verschiedener Aminothiazoliumderivate. Die Kristallstrukturen von 2-Amino-2-thiazolinium-und 2-Amino-4-methylthiazoliumtetrachlorocuprat(II) EPR Spectra of Tetrachlorocuprates of Several Aminothiazolium Derivatives. The Crystal Structures of 2-Amino-2-thiazolinium and 2-Amino-4-methylthiazolium Tetrachlorocuprate(II)  
 Abstract    The tetrachlorocuprates. of the 2-aminothiazolium ion and of four of its substitution products, of 2-aminothiazolinium, and of 2-amino-4-carboxyl-thiazolidinium ions were prepared from the cor-responding heterocyclic bases, hydrochloric acid and copper(II) chloride in ethanol. The thermo-chromic compounds were characterized by their IR and electronic spectra. The EPR spectra of solutions, frozen solutions, and of the solids show the CUC14 2 ~ ion to have the structure of a flattened tetrahedron; in the case of some of the solids, distortions from D 2 d symmetry are observed. This was confirmed by two X-ray crystal structure determinations. Crystal data: 2-amino-2-thiazolinium tetrachlorocuprate, monoclinic, space group C2/c, a = 2772.8, b = 780.0, c = 1560.0 pm, ß = 112.04°, Z = 8 (R = 0.047 for 2527 observed, independent reflexions); 2-amino-4-methylthiazolium tetrachlorocuprate, triclinic. PI, a = 780.4, b = 853.4, c — 1381.4 pm, a = 103.50, ß = 99.39, y = 104.17°, Z = 2 (R = 0.041 for 3319 reflexions). In both compounds the flattened CuCl 4 2 " tetrahedron is distorted and has two bond angles in the range between 130 and 141°. The heterocyclic cations are protonated at their ring N atoms; the corresponding H atoms and the H atoms of the amino groups are involved in N — H--C1 hydrogen bonding. 
  Reference    (Z. Naturforsch. 42b, 15—22 [1987]; eingegangen am 31. Juli 1986) 
  Published    1987 
  Keywords    Aminothiazolium Derivates, Tetrachloro Cuprates, EPR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0015.pdf 
 Identifier    ZNB-1987-42b-0015 
 Volume    42 
5Author    Ernst Egert, Ursula Kliebisch, Uwe Klingebiel, Dieter SchmidtRequires cookie*
 Title    Cyclodi-und -trisilazane — Synthese, Reaktionen und Ringkopplungen Cyclodi-and -trisilazanes — Synthesis, Reactions and Ring Coupling  
 Abstract    Contrary to our expectations, a cyclotrisilazane is obtained instead of a cyclodisilazane by the reaction of the lithiated di-rerf-butyldiamino-silane with Hal 2 SiMe 2 . Mono-and disubstitution takes place in reactions of lithiated tetra-isopropyl cyclodisilazane with halogeno-silanes and -boranes. A disubstituted ring reacts with LiOC 4 H 9 -formed from LiC 4 H y and THF — to give an unsymmetrically substituted four-membered ring as proved by a crystal structure determination. Coupling of four-and six-membered rings occurs in the reaction of SiF-substituted and lithiated rings. 
  Reference    (Z. Naturforsch. 42b, 23—30 [1987]; eingegangen am 1. September 1986) 
  Published    1987 
  Keywords    Cyclosilazanes, Substitution, Ring Coupling, Crystal Structure 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0023.pdf 
 Identifier    ZNB-1987-42b-0023 
 Volume    42 
6Author    ErhardT K Haupt, Heindirk Tom Dieck, PanayotR. BontchevRequires cookie*
 Title    Solution Structures of Pyrophthalones, I Structure and Conformation of l,3-Indandionato-2(2-pyridinium)-betai'n — a 1 H/ 13 C NMR Approach  
 Abstract    receivedJune30/September8,1986 'H/ 13 C NMR, Pyrophthalones, Solvent Dependent Structure The complete analysis of the 'H/ 13 C NMR spectra of a-Pyrophthalone and related compounds demonstrates that the earlier static planar description of the molecules is invalid for polar sol-vents, and here the stability of any intramolecular hydrogen bond is small. 
  Reference    (Z. Naturforsch. 42b, 31—36 [1987]) 
  Published    1987 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0031.pdf 
 Identifier    ZNB-1987-42b-0031 
 Volume    42 
7Author    Bernward Engelen, Willi Buchmeier, HeinzDieter LutzRequires cookie*
 Title    Zur Polymorphie des Cadmiumsulfits, Kristallstrukturen von CdS0 3 -I, CdS0 3 -II und CdS0 3 -III Polymorphic Cadmium Sulfites, Crystal Structures of CdS0 3 -I, CdS0 3 -II, and CdSO r III  
 Abstract    The crystal structures of the anhydrous cadmium sulfites CdS0 3 -I (¥2 x /c, Z=4), CdS0 3 -II (P2/C, Z=8), and CdS0 3 -III (R3, Z=18 for the hexagonal cell) have been determined by means of single crystal X-ray diffraction data. The final R for the 1475, 2349, and 2138 observed reflections are 0.040, 0.034, and 0.073. Coordination of Cd is trigonal-prismatic, a hitherto unknown coordination of Cd in salts of oxoacids, in CdS0 3 -I and CdS0 3 -II, and octahedral in CdS0 3 -III. The Cd0 6 -polyhedra are arranged in two-dimensional (CdS0 3 -I) and three-dimensional (CdS0 3 -II and CdS0 3 -III) networks. S0 3 2-groups act as monodentate and in CdS0 3 -I and CdS0 3 -II also as bidentate ligands. Cd—O distances range from 224.5(3) to 244.6(3) pm, with an average of 231.5 pm for the trigonal-prismatic and of 231.0 pm for the octahedral coordination. S—O dis-tances range from 152.3(3) to 155.3(3) pm with an average of 153.7 pm, the O —S—O angles from 99.2(2) to 106.7(3)° with an average of 103.2°. 
  Reference    (Z. Naturforsch. 42b, 37—41 [1987]; eingegangen am 2. Juli/16. September 1986) 
  Published    1987 
  Keywords    Cadmium Sulfites, Crystal Structure, Sulfites 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0037.pdf 
 Identifier    ZNB-1987-42b-0037 
 Volume    42 
8Author    FranzL. Dickert, MichaelW. VonendRequires cookie*
 Title    Konkurrierende Koordination von Kronenethern, Perchloratanionen und Lösungsmittelmolekülen am Co(II)-Ion — Eine Leitfähigkeits-und NMR-Studie in Nitromethan Anions and Solvent Molecules at Co(II)-Ions — A Conductivity and NMR Study on Nitromethane  
 Abstract    The 1:1 complexes between Co(II) and the crown ethers dibenzo[24]crown-8, dibenzo[18]-crown-6 and [18]crown-6 show a molar conductivity in nitromethane which indicates coordination of even Perchlorate anions. The substitution of this anion by solvent molecules can be monitored by conductometric titrations. This procedure reveals that dibenzo[24]crown-8 and [18]crown-6 is a potent five dentate ligand whereas dibenzo[18]crown-6 strongly coordinates only via three donor atoms. The mixed complexes with crown ether and methanol show strong outer-sphere associa-tion with the Perchlorate anions, which can be confirmed by investigations with [15]crown-5 complexes. 
  Reference    (Z. Naturforsch. 42b, 42—46 [1987]; eingegangen am 15. August/17. Oktober 1986) 
  Published    1987 
  Keywords    Crown Ether, Complex Formation Ionic Conductivity, NMR Spectra 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0042.pdf 
 Identifier    ZNB-1987-42b-0042 
 Volume    42 
9Author    Roger Blachnik, Willi Buchmeier, Claudia Schneider, Ulrike WickelRequires cookie*
 Title      
 Abstract    Phosphorus Selena Iodide, 5-Iodo-2,3,6,7-tetraselena-l,4,5-triphosphabicyclo[221]heptan. Reaction of Phosphorus Selenide with Iodine, Structure of P 3 Se 4 I, 31 P NMR Spectra P 3 Se 4 I is formed by the reaction of molten P 4 Se 3 and I 2 . P 3 Se 4 I is monoclinic, space group P2,/c with the lattice parameters of a = 1130.3(3) pm, b = 654.5(2) pm, c -1420.5(4) pm, ß — 117.64(2)°. d = 3.87 gem" 3 and d v = 3.82 gem" 3 for Z = 4. The structure of the molecule is derived from the structure of a-or /?-P 4 Se 3 I 2 by the substitution of a P—I group by a Se-atom. The P—I, P —P and Se — Se bond lengths are 249.9, 219.2 and 236.9 pm. resp. The mean P—Se bond length is 225.0 pm. The molecule is stabilized by two weak intramolecular P—Se and P—I bonds, comparable to the bonding situation in a-P 4 Se 3 I 2 . The 31 P NMR spectra reveal a coalescence effect, due to equilibrium between two isomeric forms of the molecules. 
  Reference    (Z. Naturforsch. 42b, 47—51 [1987]; eingegangen am 16. Juni/21. Juli 1986) 
  Published    1987 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0047.pdf 
 Identifier    ZNB-1987-42b-0047 
 Volume    42 
10Author    Yuzo Nishida, Masataka TakeuchiRequires cookie*
 Title    Unique Reactivity of Peroxide Ion Trapped by Binuclear Iron(III) Complex  
 Abstract    Binuclear Iron(III) Complex, Peroxide Ion The (1:1) peroxide adduct of the binuclear iron(III) complex exhibited high reactivity towards 1,3-diphenylisobenzofuran, one of the efficient singlet oxygen (] zl g) quencher. The activation of the peroxide ion in this molecule was discussed in relation to the monooxygenase function of this compound. 
  Reference    (Z. Naturforsch. 42b, 52—54 [1987]; received April 23 1986) 
  Published    1987 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0052.pdf 
 Identifier    ZNB-1987-42b-0052 
 Volume    42 
11Author    Josef Geisenberger, Jürgen Erbe, Jürgen Heidrich, Ulrich Nagel, Wolfgang BeckRequires cookie*
 Title    Pseudohalogenometallverbindungen, LXV [1] Synthese von Tetrazolen und Triazolen über die 1,3-dipolare Cycloaddition an die Azid-Liganden von polymeren Cobalt(III)-und PalIadium(II)-Komplexen. Darstellung und Struktur von 5-TrichlormethyItetrazol Pseudohalogeno Metal Compounds, LXV [1] Synthesis of Tetrazoles and Triazoles via 1,3-Dipolar Cycloaddition to the Azido Ligands of Polymerie Cobalt(III) and Palladium(II) Complexes. Synthesis and Structure of 5-Trichloromethyltetrazole  
 Abstract    The cycloaddition of nitriles and of dimethylacetylenedicarboxylate to the azide ligand of polymeric Schiff Base cobalt(III) and phosphine palladium(II) complexes gives the corresponding tetrazolate and triazolate complexes from which the heterocycles could be cleaved by hydrogen chloride. Usually the yields are low; if the heterocycle is soluble in ether or sublimable, yields up to 30% have been obtained. Using this method the hitherto unknown 5-trichlormethyltetrazole could be prepared which was characterized by an X-ray structural analysis. Similarly, the cyclo-addition of azido(tetraphenylporphinato)cobalt(III) with nitriles, cyclohexylisocyanide and Me0 2 CC=CC0 2 Me affords the corresponding complexes with heterocyclic ligands. The prepa-ration of tetraphenylporphyrinato(tricyanmethanido)cobalt(III), (TPP)CoN-CC(CN) 2 , is reported. 
  Reference    (Z. Naturforsch. 42b, 55—64 [1987]; eingegangen am 24. Juli 1986) 
  Published    1987 
  Keywords    Tetrazoles, Triazoles, Polymerie Schiff Base Cobalt(III) Complexes, Phosphine Palladium Complexes with Azide, Tetrazolate and Triazolate Ligands 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0055.pdf 
 Identifier    ZNB-1987-42b-0055 
 Volume    42 
12Author    Max Herberhold, Wolfgang Bühlmeyer, Alfred Gieren, Thomas Hübner, J. WuRequires cookie*
 Title      
 Abstract    Fragmentation of bis(rm-butyl) sulfur diimide, S(NBu') 2 (la), in the presence of Ru 3 (CO)i 2 leads to a yellow tetrahedrane-type complex Ru 2 (CO) 6 (Bu r NS) (3a) containing rer/-butyl sulfur imide as a six-electron ligand. According to the X-ray structure determination the N —S bond (1.716 Ä) is arranged perpendicular to the Ru —Ru axis (2.661 Ä). 
  Reference    (Z. Naturforsch. 42b, 65—70 [1987]; eingegangen am 3. September 1986) 
  Published    1987 
  Keywords    Di(rm-butyl) Sulfur Diimide, tert-Butyl Sulfur Imide, Ruthenium Complex, Tetrahedrane Structures 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0065.pdf 
 Identifier    ZNB-1987-42b-0065 
 Volume    42 
13Author    Heindirk Tom Dieck, Ingo KleinwächterRequires cookie*
 Title    Rutheniumkomplexe mit Diazadienen, VI [1] f/ 6 -Cycloheptatrien-und ?7 4 -Norbornadien-diazadien-ruthenium(0)-Komplexe Ruthenium Complexes with Diazadienes, VI [1] ^ 6 -Cycloheptatriene-and >; 4 -Norbornadiene-diazadiene-ruthenium(0) Complexes  
 Abstract    Reduction of [(cyclo-C 7 H 8)RuCl 2 ]2 in the presence of a diazadiene RN-CH—CH=NR (DAD; R = 2-C3H7) gives red, airsensitive, sublimable ()/ 6 -C 7 H 8)Ru(DAD) (5). A rigid structure on the basis of the 'H NMR spectrum is excluded. On the other hand pentacoordinate complexes [(j/ 4 -ttor-C 7 H 8)Ru(DAD)P(C 6 H 5) 3 ] (8) or [(^ 4 -«or-C 7 H 8)Ru(DAD)CO] (9) have rigid, C s -sym-metric, square-pyramidal structures. They are obtained by chemical or irreversible electro-chemical reduction of [(>7 4 -rcor-C 7 H 8)Ru(DAD)Cl 2 ] to [(^ 4 -nor-C 7 H 8)Ru(DAD)(solv)] (7) (solv = tetrahydrofuran or acetonitrile) and addition of phosphine or carbon monoxide. 7, in non-coor-dinating solvents, is a stereospecific catalyst for the 1-alkene —trans-2,.. ,-alkene isomerization. 
  Reference    (Z. Naturforsch. 42b, 71—76 [1987]; eingegangen am 1. September 1986) 
  Published    1987 
  Keywords    Ruthenium(O) Complexes, Diazadienes, Cycloheptatriene, Norbornadiene 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0071.pdf 
 Identifier    ZNB-1987-42b-0071 
 Volume    42 
14Author    Udo Kunze, Rolf TittmannRequires cookie*
 Title    Phosphinsubstituierte Chelatliganden, XXIII [1] Darstellung und NMR-Spektren von Alkyl-arylphosphinothioformamiden, R(Ph)PC(S)NHMe Phosphine-Substituted Chelate Ligands, XXIII [1] Synthesis and NMR Spectra of Alkyl-arylphosphinothioformamides, R(Ph)PC(S)NHMe  
 Abstract    A series of alkyl-arylsubstituted N-methyl phosphinothioformamides, R(Ph)PC(S)NHMe (2 a—g), with varying bulkiness of the alkyl rest was synthesized from the racemic secondary phosphines la—g and methyl isothiocyanate. 'H and 13 C NMR spectra of 2a—g reveal signal sets of diastereotopic nuclei due to the asymmetry of the molecule. The chemical shift and coupling constants were confirmed by simulation in case of 2b, c. The vicinal 31 P— 13 C cou-plings of the menthyl and neomenthyl compounds 2f, g show an "anti-Karplus" behaviour CJ(gauche) > ? J(trans)) and allow the conformational assignment of the alicyclic group. The 31 P chemical shifts of 2a—d give a linear correlation with the cone angle of the alkyl substituents quoted from literature. 
  Reference    (Z. Naturforsch. 42b, 77—83 [1987]; eingegangen am 8. August 1986) 
  Published    1987 
  Keywords    Alkyl-arylphosphinothioformamides, Menthyl and Neomenthyl Derivatives, NMR Spectra, Conformational Analysis, Substituent Influence 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0077.pdf 
 Identifier    ZNB-1987-42b-0077 
 Volume    42 
15Author    Richard Neidlein, Dagmar Knecht, Alfred Gieren, Catalina Ruiz-PérezRequires cookie*
 Title      
 Abstract    The synthesis of 1 by reaction of phenanthro[9,10-c]-l,2,5-selenadiazole with ethylmagnesium-bromide and TeCI 4 is described; the X-ray structure analysis is reported. 
  Reference    (Z. Naturforsch. 42b, 84—90 [1987]; eingegangen am 9. August 1986) 
  Published    1987 
  Keywords    Chalkogen-Diimides, 1, 2, 5-Telluradiazole, X-Ray 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0084.pdf 
 Identifier    ZNB-1987-42b-0084 
 Volume    42 
16Author    Rahman, Sajida Khanum, Yasmin Badar, Kaneez Fatima, Yusuf Ahmad, H.E JRequires cookie*
 Title    Atta-ur  
 Abstract    Continuing studies on the leaves of Rhazya stricta have resulted in the isolation of a new Picralima alkaloid, N h -methyl strictamine 2. 
  Reference    (Z. Naturforsch. 42b, 91—93 [1987]; received June 10 1986) 
  Published    1987 
  Keywords    Rhazya stricta, Alkaloids, Indolenine, 13 C NMR Spectra, Mass Spectra 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0091.pdf 
 Identifier    ZNB-1987-42b-0091 
 Volume    42 
17Author    M. Hammouda, W. S. Hamama, E. M. AfsahRequires cookie*
 Title    A Study on the Mannich Reaction with l-Phenylamino-3-indenone  
 Abstract    Mannich Reaction. l-Phenylamino-3-indenone Mannich reaction of the title compound 1 with formaldehyde and morpholine, piperidine or piperazine afforded the Mannich bases 3—5 respectively, whereas the indeno[1.2-d]pyrimidines (6—7) were obtained where primary amines were used. Treatment of 2 with formaldehyde gave benz[b]indeno-diazepine (8). The reaction of formaldehyde with 1 was also investigated. 
  Reference    (Z. Naturforsch. 42b, 94—96 [1987]; received May 9. 1986) 
  Published    1987 
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 Identifier    ZNB-1987-42b-0094 
 Volume    42 
18Author    RolfW. Saalfrank, Franz Schütz, Hans-Ulrich HummelRequires cookie*
 Title    Vinylacetylene aus 1.3-Bis(dialkylamino) -1,3-diethoxyallenen und Alkylidenmalonylchloriden. Kristall-und Molekülstruktur von 3-(Diphenyl)methylen-6-diisopropylamino-5-diisopropyIaminocarbonyl- 2.4-dioxo-3,4-dihydro-2H-pyran [1] Vinylacetylenes from l,3-Bis(dialkylamino)-l,3-diethoxyallenes and Alkylidenemalonyl Chlorides. Crystal and Molecular Structure of 3-(Diphenyl)methylene-6-diisopropylamino-5-diisopropylaminocarbonyl- 2,4-dioxo-3,4-dihydro-2H-pyrane [1]  
  Reference    (Z. Naturforsch. 42b, 97—100 [1987]; eingegangen am 14. Juli 1986) 
  Published    1987 
  Keywords    Tetra Donor Substituted Allenes, Vinylacetylenes, 3-Methylene-2, 4-dioxo-3, 4-dihydro-2H-pyranes, Crystal Structure 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0097.pdf 
 Identifier    ZNB-1987-42b-0097 
 Volume    42 
19Author    Karl Folkers, Cyril Bowers, Xiao Shao-Bo, Pui-Fun, Louisa Tang, Minoru Kubota, Janusz Stepinski, Teresa KubiakRequires cookie*
 Title    Activities of Antagonists of the Luteinizing Hormone Releasing Hormone with Emphasis on Positions 1, 5 and 6 and on Positions 1, 2 and 3  
 Abstract    Analogs of the luteinizing hormone releasing hormone (LHRH) which are antagonists for controlling ovulation require potency and negligible release of histamine as a side effect. Forty analogs were designed, synthesized and bioassayed in two groups with emphasis upon positions 1, 5 and 6 and upon positions 1, 2 and 3. N-Ac-D-2-Nal 1 , D-pClPhe 2 , D-3-Pal 3 , Ser 4 , Tyr 5 . D-Lys 6 , 
  Reference    (Z. Naturforsch. 42b, 101—106 [1987]; received July 18 1986) 
  Published    1987 
  Keywords    Luteinizing Hormone Releasing Hormone, a«f/-Ovulatory Activity, Peptide, Antagonist, Histamine Release 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0101.pdf 
 Identifier    ZNB-1987-42b-0101 
 Volume    42 
20Author    Abdel Moneim El-Torgoman, Mohamed Salah, El-Kousy, Zaghloul El, -Shahat KandeelRequires cookie*
 Title    Nitriles in Heterocyclic Synthesis: The Reaction of 2-Thiocarbamoyl Cinnamonitriles with Active Methylene Reagents  
 Abstract    Heterocyclic Synthesis, 2-Thiocarbamoyl Cinnamonitriles Substituted pyridin-2-thiones, 2-pyridones, thiopyrans and pyranoazoles could be synthesized via the reaction of 2-thiocarbamoyl cinnamonitriles with some active methylene reagents. 
  Reference    (Z. Naturforsch. 42b, 107—111 [1987]; received March 25/July 31 1986) 
  Published    1987 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0107.pdf 
 Identifier    ZNB-1987-42b-0107 
 Volume    42 
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