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Facet section ZfN Section B:Volume 048 [X]

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1	Author		Requires cookie*
	Title	Kristallstrukturen von Li6MgBr8 und Li2MgBr4
	Abstract	C rystal Structure o f Li6M g B r8 and Li2M gB r4 M ichael Schneider, P eter K uske und H einz D ieter Lutz* U niversität G H Siegen, A norg an isch e C hem ie I, D-W -5900 Siegen Herrn Prof. Z. N aturforsch. 48b, 1 -6 (1 9 9 3); eingegangen am 24. A ugust 1992 C rystal S tructure, N eu tro n D iffraction, L ithium M agnesium Brom ide, Suzuki Type, X -R ay T he crystal structures o f the fast ionic c o n d u cto rs Li6M gB r8 an d Li2M gBr4 oC 14 and cF 56 were determ ined by single crystal X -ray diffractio n and n eu tro n pow der studies, respectively. A t am bient_tem perature, Li6AfBrs (M = Mg, M n) crystallize in a Suzuki-type stru ctu re (space gro u p F m 3 m , Z = 4, Li6M gB r8: a = 1098.0(1) pm, 114 unique reflections, R = 0.037). Li2M gB r4 oC 14 crystallizes in a S n M n 2S4-type structure (space group C m m m , Z = 2, a = 777.94(2), b = 1104.25(4), a n d c -386.55(1) pm , R, = 0.073, 318 K), the high-tem p eratu re polym orph (H T M I) in the Li2M n B r4 c F 56 type (space gro u p F d 3 m , Z = 8, a = 1124.55(4) pm , R, = 0.052, 673 K). These stru ctu re types are m ore o r less ordered N aC l superstructures. The therm al ellipsoids o f the lithium ions are discussed in term s o f the cond u ctio n pathw ays and the ord er-d iso rd er phase tran sitio n s observed.
	Reference	(Z. Naturforsch. 48b, 1 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0001
	Volume	48

2	Author		Requires cookie*
	Title	Erste Kristallstruktur eines gemischten A l-M g-A lkoholates
	Abstract	F irst C rystal S tructure D eterm ination o f an A lum inium M agnesium A lkoxide Jörg Saßm annshausen M ax -P lan ck -In stitu t für F estkörperforschung, H eisenbergstraße 1, D -W -7000 S tu ttg art 80 R a lf Riedel*
	Reference	(Z. Naturforsch. 48b, 7 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0007
	Volume	48

3	Author	H. Em Z-Jürgen, K. Beister, Arl Syassen	Requires cookie*
	Title	Pressure-Induced Phase Transition of the Alkali Metal Amalgam KHg2
	Reference	(Z. Naturforsch. 48b, 11 [1993])
	Published	1993
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0011.pdf
	Identifier	ZNB-1993-48b-0011
	Volume	48

4	Author		Requires cookie*
	Title	Untersuchungen zur Anionendefektverteilung in Sr2M n 0 4.v
	Abstract	Investigation on the D istrib u tio n o f A nion Vacancies in Sr2M n 0 4.v R. Kriegei3 *, H. B o rrm an n b, A. Sim onb und A. Feltz3
	Reference	(Z. Naturforsch. 48b, 15 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0015
	Volume	48

5	Author	Crystal	Requires cookie*
	Title	Kristallstruktur von Bromchlormethyleniminium-hexachloroantimonat BrCIC=NH2+SbCl6
	Abstract	S tructure o f B rom ochlorom ethyleneim inium H exachloroantim onate BrCIC = N H 2+SbC l6" R. M inkw itz*, W. M eck stro th und H. P reut U niversität D o rtm u n d , Fachbereich Chem ie, P ostfach 500500, D-W -4600 D o rtm u n d 50 Z. N aturforsch. 48b, 1 9 -2 2 (1 9 9 3); eingegangen am 18. A u gust 1992 D ihalidom ethyleneim inium Salts, C rystal S tructure B rom ochlorom ethyleneim inium h ex ach lo ro an tim o n ate BrClC = N H 2+SbC l6" crystallizes in the space group P 2 ,/c w ith a = 979.6(5), b = 1140.5(5), c = 2162.1(10) pm , ß = 102.45(4)° and Z = 8. It is isostructural w ith C l2C = N H ,+S bC l6~.
	Reference	(Z. Naturforsch. 48b, 19 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0019
	Volume	48

6	Author		Requires cookie*
	Title	Kristallstruktur des Cadmiumthiocyanat-Hexamethylentetramin-Addukts Cd(SCN)2 * C6H 12N 4 * 2 H 20
	Reference	(Z. Naturforsch. 48b, 23 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0023
	Volume	48

7	Author	H. Einrich, Uwe Lay, M. Ichael Leise, Laszlo Zsolnai	Requires cookie*
	Title	Propargyl-, Allenyl-und Alkinyl
	Abstract	A norganisch-C hem isches In stitut der U niversität, Im N euenheim er Feld 270, D-W -6900 H eidelberg 1 Z. N atu rfo rsch . 48b, 2 7 -3 6 (1993); eingegangen am 23. M ärz 1992 P ropargyl, Allenyl and Alkynyl P hosphanes, C o o rd in atio n A bility, Isom erization, C rystal S tructure T he synthesis and reactivity o f non-co o rd in ated an d c o o rd in ated pro p arg y l pho sp h an es are discussed. T he isom erization o f the propargyl unit in (R)P(C 1)(C H 2C = C H) (3) (R = 2,4,6-'B u3C 6H 20) in the presence o f N E t3 yields the^ allenyl su b stitu ted p ro d u ct (R)P(C1)(CH = C = C H 2) (4). H ow ever, in the presence o f H N E t2 the dim ethylenecyclobutane 7 is form ed. D ifferent synthetic pathw ays for the p rep aratio n o f L "M P(Ph)m(C H 2C = C H)3 m com plexes (m = 2: L"M = (//5-C 5H 5)(C O)2M n: 10a; L"M = (C O)5Cr: 10 b; m = 1: L"M = (^5-C 5H 5)(C O)2M n: 13a; L"M = (?/5-C 5H 4M e)(C O)2M n: 13b) are described. T he synthesis o f the alkynyl substituted phosp h an e com pounds L"M P(Ph)m(C = C R)3 m (m = 2: R = Ph, LnM = (/;5-C 5H 5)(C O)2M n: 20a; L"M = (C O)5Cr: 20b; R = "Bu, L"M = (C O)5Cr: 20c; m = 1: R = Ph, L"M = (/75-C 5H 5)(C O)2M n: 22) was also possible. The reaction o f (>/5-C 5H 4M e)(C O),M n P P h (C H ,C = C H)2 (13 b) w ith C o 2(C O)8 affords in high yields (V5-C 5H 4M e)(C O)2M nPPh[(?/2-C H 2C = C H)C o 2(C O)6]2 (15). All new co m pounds have been characterized by analytical a n d spectroscopic d a ta (IR , 'H -, 13C { 'H } -, 31P { 'H } -N M R , M S) an d (;/5-C 5H 5)(C O)2M n P (P h)(C H 2C = C H)2 (13a) by X -ray analysis.
	Reference	(Z. Naturforsch. 48b, 27 [1993])
	Published	1993
	Keywords	Phosphane, Synthese, Reaktivität, Isomerisierung* Propargyl-, Allenyl-and A lkynyl-Phosphanes, Synthesis, R eactivity, Isom erization
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0027.pdf
	Identifier	ZNB-1993-48b-0027
	Volume	48

8	Author	ZahideÖ. Zer, SaimÖ. Zkar, H. Ö. Pam	Requires cookie*
	Title	[^-Bis(dialkylphosphino)alkane]-bis[pentacarbonylmetal(0)] Complexes of the Group 6 B Elements: Synthesis and Spectroscopic Study
	Reference	(Z. Naturforsch. 48b, 37 [1993])
	Published	1993
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0037.pdf
	Identifier	ZNB-1993-48b-0037
	Volume	48

9	Author		Requires cookie*
	Title	Darstellung und spektroskopische Charakterisierung der Oxorhenate(V)
	Abstract	IReO IJ-und [ReO(SCF3)4r P rep aratio n and Spectroscopic C haracterization o f the O xorhenates(V), [R eO I4]~ and [R eO (S C F3)4]" W. Preetz* und W. L ierka
	Reference	(Z. Naturforsch. 48b, 44 [1993])
	Published	1993
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0044.pdf
	Identifier	ZNB-1993-48b-0044
	Volume	48

10	Author	D.	Requires cookie*
	Title	Die Bestimmung von W asserstoff in Metallen, Metallhydriden und Hydridhalogeniden
	Abstract	eterm ination o f H ydrogen in M etals, M etal H ydrides and H ydrid H alides R oland Eger, H ansjürgen M attau sch und A rn d t Sim on* M ax-P lanck -In stitu t für F estk ö rp erfo rsch u n g , H eisenbergstraße 1, D -W -7000 S tu ttg a rt 80 Z. N aturforsch . 48b, 4 8 -5 1 (1993); eingegangen am 2. O k to b er 1992 H ydrogen, M etals, R are E arth H ydrides, R are E arth H ydridehalides The hydrogen con ten t in N b H 0 l77, G d H 2, and the chlorides and brom ides o f the type LnXH" (Ln = Y, G d; 0.67 < / ? < 1.00) is determ ined. T he sam ples are b u rn t in an oxygen a t m osphere and the H 20 produced in the com bustion process is potentio m etrically titrated with an accuracy o f ± 3% (K arl-F ischer m ethod).
	Reference	(Z. Naturforsch. 48b, 48 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0048
	Volume	48

11	Author	W. Olfgang Jeitschko, R. Einhold, B. Rink, PeterG. Pollmeier	Requires cookie*
	Title	The Ternary Uranium Transition Metal Phosphides UV5P3, UCr5P3, and UMn5P 3
	Abstract	A norganisch-C hem isches In stitu t der U niversität M ünster, W ilhelm -K lem m -Straße 8, D -W -4400 M ünster Z. N aturforsch . 48b, 5 2 -5 7 (1993); received Septem ber 1, 1992 C rystal S tructure, M agnetic Susceptibility, Tin Flux, S tructural R elationships The title co m p o u n d s were p rep ared from prereacted sam ples o f the elem ental co m p o n en ts by arc-m elting. U C r5P 3 was also o b tain ed from a tin flux. U V 5P 3 and U C r5P 3 crystallize w ith a new structu re type, w hich w as determ ined from X -ray d ata o f a tw inned crystal o f U C r5P3: P 2 1/m , a = 959.1(2), b = 370.95(6), c = 696.7(1) pm , ß = 100.05(3)°, Z = 2,R = 0.030 for 827 stru ctu re factors and 29 variable param eters. U M n ,P , is isotypic w ith Y C o 5P 3. The structure was refined to a residual o f R = 0.054 for 455 structure factors and 28 variables. U C r5P3 has a relatively high, alm ost tem p eratu re independent param ag n etic susceptibility as is frequently observed for m etallic u ran iu m com pounds. The crystal stru ctu res o f these p h o s phides are discussed to g eth er w ith those o f oth er phosphides and silicides o f sim ilar co m p o si tion.
	Reference	(Z. Naturforsch. 48b, 52 [1993])
	Published	1993
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0052.pdf
	Identifier	ZNB-1993-48b-0052
	Volume	48

12	Author		Requires cookie*
	Title	Reaktive E=C(p-p)^--System e, XXXIV [1]
	Abstract	Addition von Alkoholen oder primären Aminen an Phosphaalkene F3C P=C(F)O R . Neue Trifluormethylphosphane und -phosphaalkene
	Reference	(Z. Naturforsch. 48b, 58 [1993])
	Published	1993
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0058.pdf
	Identifier	ZNB-1993-48b-0058
	Volume	48

13	Author		Requires cookie*
	Title	Darstellung und Eigenschaften von Derivaten des 4,5-Benzo-2,3-dihydro-\ ,3-diborols
	Abstract	Synthesis and Properties o f D erivatives o f the 4 ,5-Benzo-2,3 -d ih y d ro -1,3-diborole H a rtm u t Schulz, T hom as D eforth und W alter Siebert*
	Reference	(Z. Naturforsch. 48b, 68 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0068
	Volume	48

14	Author	O. Liver, Steigeim Ann, Peter Bissinger, H. Ubert, Schm Idbaur	Requires cookie*
	Title	,1,1,1 -Tetrakis[triorganylphosphineaurio(I)]ethanium(+) Tetrafluoroborates - Hypercoordinated Species Containing [H3C -C (A u L )4I+ Cations
	Abstract	Auriophilicity, Gold(I) Phosphine Complexes, Ethane-tetraaurio(I) Com pounds, X-Ray H ypercoordinate, tetraaurated carbon-complexes of the type [H3C -C (A u P R 3)4]+BF4~, R = Ph (1), R = C6H u (2), (PR3)2 = l,2-C 6H 4(C H 2C H 2P Ph2)2 (3) have been prepared by the reac tion o f the appropriate (phosphane)gold(I) chlorides with l,l,l-tris(dim ethoxyboryl)ethane H 3C -C [B (O M e)2]3 in the presence of CsF. The products have been characterized by standard analytical and spectroscopic methods, including single crystal X-ray analyses of 1 and 2. In each case the pentacoordinated carbon atoms have been located at the centre of a square pyr-amide built up by a methyl group at the apex and four gold atoms forming the base with short Au • • • Au distances of about 2.85 A, which strongly contribute to the form ation and stability of these species.
	Reference	(Z. Naturforsch. 48b, 72—78 [1993]; received September 10 1992)
	Published	1993
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	Identifier	ZNB-1993-48b-0072
	Volume	48

15	Author	K. Arl Hensen, PeterW. Ag, N. Er+	Requires cookie*
	Title	Die Kristallstruktur der Verbindung N-Trimethylsilyl-3,4-Dimethylpyridiniumbromid The C rystal Structure o f N -T rim ethylsilyl-3,4-dim ethylpyridinium Brom ide
	Abstract	Trimethylbromosilane and 3,4-lutidine form a 1:1 com pound which is stable at room tem perature. Single crystals of this com pound can be isolated by sublimation. It crystallizes in the orthorhom bic space group P 2,2,2, with lattice constants a = 737,08(9) pm, b = 1295,7(1) pm, c = 1318,8(3) pm. The crystal structure was refined to Rw = 0,042 and proves an ionic struc ture.
	Reference	(Z. Naturforsch. 48b, 79—81 [1993]; eingegangen am 21. Februar 1992)
	Published	1993
	Keywords	Trimethylbromosilane, 3, 4-Dimethylpyridine, Addition Com pound, Crystal Structure
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	Identifier	ZNB-1993-48b-0079
	Volume	48

16	Author		Requires cookie*
	Title	Zur Kenntnis von Gadolinium(III)-sulfit Dihydrat Gd2( S 0 3)3 * 2 H 20
	Reference	(Z. Naturforsch. 48b, 82 [1993])
	Published	1993
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	TEI-XML for	default:Reihe_B/48/ZNB-1993-48b-0082.pdf
	Identifier	ZNB-1993-48b-0082
	Volume	48

17	Author	LinY. Angab, PeterG. Jonesa, R. Einhard, S. Chm	Requires cookie*
	Title	Synthese und Charakterisierung von Halogen-phosphor(III)- Derivaten des 8-Hydroxychinolins. Röntgenstrukturanalyse von 8-[Phenyl(chloro)-phosphito]-chinolin
	Abstract	Synthesis and C haracterization o f H alo g en -p h o sp horus(III) D erivatives o f 8-H ydroxyquinoline. X -R ay Structure A nalysis o f 8-[Phenyl(chloro)phosphito]-quinoline 8-Hydroxyquinoline, N M R Spectra, X-Ray The reaction of 8-trimethylsiloxyquinoline, 2 with PC13, PhPCl2, and P hPF 2 has furnished the corresponding 8-quinolyl halophosphite derivatives, 3 -5 . The synthesis of two metal com plexes, 8 and 9, of 4 with Au(I) and Pt(II) is described. The new com pounds were characterized by elemental analysis and by 'H and 31P N M R spectroscopy. A single crystal X-ray diffraction study of 4 has been conducted; a short intramolecular P -N contact (230.9 pm) and a long P -C l bond (218.7 pm) were observed.
	Reference	(Z. Naturforsch. 48b, 85—89 [1993]; eingegangen am 2. April 1992)
	Published	1993
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	Identifier	ZNB-1993-48b-0085
	Volume	48

18	Author	C. M. Ller+, P. Böttcher	Requires cookie*
	Title	Darstellung und Kristallstruktur des Bis(dicyclohexylammoniuni)-lieptasulfids \|H 2N(C6H " )2]2S7
	Abstract	P rep aratio n and C rystal S tructure o f B is(dicyclohexylam m onium)-heptasulfide [H 2N (C 6H 11)2]2S7 The reaction of dicyclohexylamine and sulphur (molar ratio 2:7) with H 2S in a mixture of dimethylformamide and formamide yields red crystals o f bis(dicyclohexylammonium)hepta-sulfide. The com pound crystallizes in the centrosymmetric space group P2,/c, the lattice con stants are a = 9.787(2) Ä, b = 18.972(4) Ä, c = 17.118(3) Ä, ß = 96,12(2)°. The S2 7~ chain has not the common helical a//-r/-a«5-conformation, but a mixed conformation trans-cis-trans (se quence of the signs of torsion angles + h-----a n d ------*-+).
	Reference	(Z. Naturforsch. 48b, 90—9 [1993]; eingegangen am 20. Juli 1992)
	Published	1993
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	Identifier	ZNB-1993-48b-0090
	Volume	48

19	Author		Requires cookie*
	Title	2-Phosphinotetrazole und ihre Überführung in 1,3,4>2 A5-Thia-und -Selenadiazaphosphol-Dimere [1]
	Reference	(Z. Naturforsch. 48b, 93 [1993])
	Published	1993
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	Identifier	ZNB-1993-48b-0093
	Volume	48

20	Author	A. C. Aubet, V. M. Oreno, A. L. Ab Arta, J. T. Ejada	Requires cookie*
	Title	Electronic Structure Determination of Co(II)-Nucleotide Complexes by Using Magnetic and Mößbauer Emission Measurements
	Abstract	M ößbauer Emission, M etal-Nucleotide Complexes, Electronic Structure M ößbauer emission spectroscopic and susceptibility measurements of several Co(II)-nu-cleotide complexes have been carried out. The electronic structure derived from these data for the Co(II) central cation has been related to the distortion and the symmetry of its environ ment. The susceptibility data are indicative of short antiferromagnetic ordering in the majority of the samples. For the hydrated Co-5'UM P (5'-uridine-monophosphate) and Co-5'CM P (5'-cytidine-monophosphate) complexes, magnetic models involving Co(II) dimers and linear chains, respectively, are proposed to explain the susceptibility data observed below 50 K.
	Reference	(Z. Naturforsch. 48b, 98—106 [1993]; received August 11 1992)
	Published	1993
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	Identifier	ZNB-1993-48b-0098
	Volume	48

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