Go toArchive
Browse byFacets
Bookbag ( 0 )
'silyl radicals' in keywords
Results  1 Item
Sorted by   
Section
Publication Year
1996 (1)
1Author    C. Kerst, P. Potzinger, H. Gg, WagnerRequires cookie*
 Title    Reaction of Trimethyl-and Dimethyl-Silyl Radicals with Pentamethyldisilane  
 Abstract    The rate constant for the H atom abstraction of trimethylsilyl radicals from pentamethyldisilane k (4) (&(4)) was measured relative to the trimethylsilyl combination reaction k(3). A value for • ]/k (3) = (8.53±0.08) • 10" 11 cm 3 ' 2 s~ 1/2 was obtained. For the dimethylsilyl radical, a smaller value for the corresponding rate constant ratio (5.9 + 0.2) • 10" 11 cm 3 ' 2 s" 1/2 was measured, and this was attributed to a disproportionation reaction between the dimethylsilyl and the pentamethyldisilyl radical leading to dimethylsilylene. 
  Reference    Z. Naturforsch. 51a, 102—104 (1996); received October 28 1995 
  Published    1996 
  Keywords    Hydrogen abstraction, silyl radicals, pentamethyldisilane, disproportionation reaction 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_A/51/ZNA-1996-51a-0102.pdf 
 Identifier    ZNA-1996-51a-0102 
 Volume    51