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1Author    ThomasK. Aukorat, Reinhard SchmutzlerRequires cookie*
 Title    N,N',N'-Trimethylethylendiamin-substituierte Phosphor(III)-Verbindungen und deren Oxidation zu Derivaten mit tetra-und pentakoordiniertem Phosphor N,N',N'-Trim ethylethylenediam ine-Substituted Phosphorus(III) Com pounds and their Oxidation to Derivatives with Four-and Five-Coordinated Phosphorus  
 Abstract    A study was made o f the intramolecular donor-acceptor interaction in N ,N',N'-trim ethyl-ethylenediamine-substituted phosphorus com pounds, involving A3-, A4-and A5-phosphorus atom s, as a function o f the nature o f the substituents at phosphorus. The reaction o f N-trim ethylsilyl-N,N',N'-trim ethylethylenediam ine (1) with (Pr'0)2PCl furnished the acyclic, trimethylethylenediamine-substituted phosphorus(III) compound 4. There is no N M R spec­ troscopic evidence for an intramolecular donor-acceptor interaction between the phosphorus atom and the nitrogen atom o f the dim ethylam ino group in 4. The oxidation o f the trivalent phosphorus atom in 4 and in the related com pound 5 by sulfur, selenium, tetrachloro-o-benzoquinone, and hexafluoroacetone led to the corresponding A4P com pounds 6 -9 and to the A5P com pounds 10 and 11. N o intramolecular donor-acceptor interaction could be detected in any o f these products. There was no reaction between 5 and elemental tellurium. The reac­ tion products were characterized by N M R spectroscopy, mass spectrometry, and by elemental analysis. 
  Reference    Z. Naturforsch. 47b, 275 (1992); eingegangen am 29. August 1991 
  Published    1992 
  Keywords    N, N', N'-Trim ethylethylenediam ine, D o n o r-Acceptor Interaction, Oxidizing Agents, N M R Spectra, M ass Spectra 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0275.pdf 
 Identifier    ZNB-1992-47b-0275 
 Volume    47 
2Author    Thom As, K. Aukorat, PeterG. Jones, Reinhard SchmutzlerRequires cookie*
 Title    Das 7,8-Benzo-5-chloro-1,4,4-trimethyl-l-aza-4-azonia-6,9-dioxa-5 A5-phospha- spiro[4.4]nonanyl-Kation: Röntgenstrukturanalyse und temperaturabhängige ^ -N M R -Spektren4]nonanyl Cation: X-Ray Crystal Structure Determination and Variable 'H NMR Spectra  
 Abstract    The 7,8-Benzo-5-chloro-1,4,4-trimethyl-1 -aza-4-azonia-6,9-dioxa-5/l5-phosphaspiro[4. The 'H N M R spectrum o f the spirophosphorane 3 at room temperature indicates dynamic behaviour o f the cation. The low-temperature 'H N M R spectra o f 3 exhibit two sets o f dou­ blets for the protons o f the diastereotopic N (C H 3)2 groups. The free enthalpy o f activation for the dynamic process was determined (58.6 KJ/mole). In the reaction o f 3 with sodium tetra-phenylborate the crystalline com pound, 4, involving the non-coordinating anion, [B(C6H 5)4]~, was obtained. The X-ray crystal structure analysis o f 4 reveals the presence o f a five-membered ring, formally as a result o f intramolecular donor-acceptor interaction between the nitrogen atom o f the N (C H 3)2 group and phosphorus. The geometry at phosphorus deviates som ewhat from ideal trigonal bipyramidal. 
  Reference    Z. Naturforsch. 47b, 755 (1992); eingegangen am 9. September 1991 
  Published    1992 
  Keywords    N, N', N'-Trim ethylethylenediam ine, A zonium Salt, Donor-Acceptor-Interaction, Temperature-Dependent N M R Spectra, X-Ray Crystal Structure 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0755.pdf 
 Identifier    ZNB-1992-47b-0755 
 Volume    47 
3Author    R. Olf Minkwitz, Jens JakobRequires cookie*
 Title    Uber die Bildung von N,N-Bistrifluormethylhydroxylammoniumsalzen (CF3)2N(X)OX+MF6-(X = H, D; M = As, Sb) On the Formation o f N,N-Bistrifluoromethylhydroxylammonium Salts (CF3)2N(X)O X+MF6-(X = H, D; M = As, Sb)  
 Abstract    The preparation of the N,N-Bistrifluoromethylhydroxylammonium hexafluorometallates (CF3)2N(X)OX+MF6~ (X = H, D; M = As, Sb) is reported. The new compounds were cha­ racterized by IR, Raman, Mass, 'H , ,9F and l3C NM R spectroscopy. In addition we present our approach to the preparation of H-subsituted N,N-Bistrifluoromethylhydroxylammonium hexafluorometallates (C F ^ N (Y)O H +M F6~ (Y = C H 3, Cl, F; M = As, Sb). 
  Reference    Z. Naturforsch. 52b, 958—964 (1997); eingegangen am 12. Mai 1997 
  Published    1997 
  Keywords    N, N-Bistrifluoromethylhydroxylammonium Hexafluoroarsenate, N, N-Bistrifluoromethylhydr-oxylammonium Hexafluoroantimonate, Vibrational Spectra, NMR Spectra, Mass Spectra 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0958.pdf 
 Identifier    ZNB-1997-52b-0958 
 Volume    52 
4Author    Christina Ergezinger, Frank Weller, Kurt DehnickeRequires cookie*
 Title    Amidinatokomplexe von Bor, Aluminium, Gallium, Indium und Zinn Die Kristallstrukturen von Ph-C(NSiMe 3 ) 2 AICI 2 und Ph-C(NSiMe 3 ) 2 SnCl 3 Amidinato Complexes of Boron, Aluminium, Gallium, Indium, and Tin The Crystal Structures of Ph-C(NSiMe 3 ) 2 AlCl 2 and Ph-C(NSiMe 3 ) 2 SnCl 3  
 Abstract    The trichlorides of aluminium, gallium, and indium, as well as boron tribromide and tin tetra-chloride react with N,N,N'-tris(trimethylsilyl)benzamidine to form the monomeric N.N'-bis-(trimethylsilyl)benzamidinato complexes Ph-C(NSiMe,) 2 MX 2 (M = B, Al. Ga, In; X = Cl, Br) and Ph —C(NSiMe 3) 2 SnCl 3 , respectively. All compounds have been characterized by their IR spectra, two of them by X-ray diffraction studies. Ph — C(NSiMei) 2 AlCl 2 : Space group C2/c, Z = 4, 1152 independent observed reflexions, R = 0.052. Lattice dimensions (19 °C): a = 1558.6(1), b = 1116.6(1), c = 1307.0(1) pm, ß = 115.17(1)°. The compound forms monomeric molecules, in which the aluminium atom is tetra-hedrally coordinated by two chlorine atoms and by the two nitrogen atoms of the benzamidinato chelate. Bond length A1N = 188.2 pm. Ph — C(NSiMe^) 2 SnCU: Space group PI, Z = 2, 3293 independent observed reflexions, R = 0.034. Lattice dimensions (19 °C): a = 980.1(1), b = 1025.9(1), c = 1230.5(2) pm. a = 68.40(1)°, ß = 87.71(1)°, y — 68.92(1)°. The compound forms monomeric molecules, in which the tin atom is five-coordinated by three chlorine atoms and by the two nitrogen atoms of the benzamidinato chelate. Bond lengths SnN = 213.5 and 215.2 pm. 
  Reference    Z. Naturforsch. 43b, 1621—1627 (1988); eingegangen am 18. August 1988 
  Published    1988 
  Keywords    N, N'Bis-(trimethylsilyl)amidinato Complexes, Synthesis, IR Spectra Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1621.pdf 
 Identifier    ZNB-1988-43b-1621 
 Volume    43 
5Author    CliffordW. Fonga, HamishG. GrantRequires cookie*
 Title    Solvent Effects on the Carbon - 13 NMR Chemical Shifts and Rotational Barriers of N,N-Dimethylbenzamide - Solvent Enhanced n Polarization  
 Abstract    The 13 C NMR chemical shifts of N,N-dimethylbenzamide in thirty solvents have been measured at high dilution. The solvent induced chemical shifts (s.i.c.s.) of the carbonyl group carbon atom in twenty three solvents and the thermodynamic barriers to rotation about the C-N bond in eleven solvents are linearly related to the solvent parameter, ET(30). Multi-parametric analysis of the carbonyl s.i.c.s. indicates hydrogen bond donor effects are more important than polar effects. Rotational barriers for N,N-dimethylbenz-amide may be determined by measurement of the 13 C chemical shift of the carbonyl group in a particular solvent. The s.i.c.s. of the aromatic ring carbon atoms may be explained by the polarization of the aromatic ji electron system induced by the solvent enhanced polarization of the dimethylcarboxamido moiety. Hydrogen bonding solvents and polar solvents result in two effective dipoles on the dimethylcarboxamido moiety, which polarize the aromatic n electron system differently. 
  Reference    Z. Naturforsch. 36b, 585—595 (1981); received May 19 1980/January 21 1981 
  Published    1981 
  Keywords    Solvent Effects, 13 C NMR Spectra Rotational Barriers, N, N-Dimethylbenzamide 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0585.pdf 
 Identifier    ZNB-1981-36b-0585 
 Volume    36 
6Author    ;.M = Ti, ZrDieter Fenske, Eva Hartmann, Kurt DehnickeRequires cookie*
 Title    N,N'-Bis(trimethylsilyl)benzamidinato-Koniplexe von Titan und Zirkon. Die Kristallstrukturen von [C 6 H 5 -C(NSiMe3) 2 MCl 3 ] 2 ; M = Ti, Zr N,N'-Bis(trimethylsilyl)benzamidinato Complexes of Titanium and Zirconium. The Crystal Structures of [C 6 H 5 -C(NSiMe 3 ) 2 MCl 3 ]  
 Abstract    The N,N'-bis(trimethylsilyl)benzamidinato complexes [C 6 H 5 -C(NSiMe 3) 2 MCl 3 ] 2 (M = Ti. Zr) have been prepared by the reactions of N,N,N'-tris(trimethylsilyl)benzamidine, [C 6 H 5 — C(NSiMe 3)N(SiMe 3) 2 ] with titanium tetrachloride, and zirconium tetrachloride, respec-tively. The compounds form moisture sensitive, dark red (Ti) and white (Zr) crystals, which were characterized by crystal structure determinations. [C 6 H 5 —C(NSiMe 3) 2 TiCl 3 ] 2 : space group P2,/rc. Z = 2, 4373 observed independent reflexions, R = 0.034. Lattice dimensions (-90 °C): a — 959.0(8); b = 1196.5(8); c = 1770.9(11) pm; ß = 93.79(4)°. [C 6 H 5 -C(NSiMe 3) 2 ZrCl 3 ] 2 : space group P2,/«. Z = 2, 3160 observed independent reflexions, R = 0.031. Lattice dimensions (-90 °C): a = 971.6(7); b = 1222.2(9); c = 1792.9(10) pm; ß = 93.51(5)°. Both complexes crystallize isotypically, forming centrosymmetric dimeric molecules via chloro bridges with bond lengths of 242.0 and 253.8 pm (Ti), and of 253.7 and 264.9 pm (Zr). The metal atoms complete their distorted octahedral surroundings with two chlorine ligands and the nitrogen atoms of the chelating amidinato ligand. The N atoms of the amidinato group are in equatorial and axial positions. This accounts for the different metal-nitrogen bond lengths of 207 pm (ax) and 199 pm (eq) in the titanium compound and 219 pm (ax) and 214 pm (eq) in the zirconium complex. 
  Reference    Z. Naturforsch. 43b, 1611—1615 (1988); eingegangen am 22. Juni 1988 
  Published    1988 
  Keywords    N, N'-Bis(trimethylsilyl)benzamidinato Complexes, Titanium, Zirconium, Syntheses, IR Spectra 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1611.pdf 
 Identifier    ZNB-1988-43b-1611 
 Volume    43 
7Author    Jan-K Arel Buijink, M. Athias, Noltemeyer Und, FrankT. EdelmannRequires cookie*
 Title    Metall-N,N  
 Abstract    -bis(trimethylsilyl)benzamidinate: Synthese und Kristallstruktur von Bis[N,N-bis(trimethylsilyl)benzamidinato)chroni(II), [P hC (N SiM e3)2l2Cr Metal-N,N'-bis(trimethylsilyl)benzamidinates: Synthesis and Crystal Structure of Bis[N,N'-bis(trimethylsilyl)benzamidinato]chromium(II), [PhC(NSiM e3)2]2Cr The preparation o f N,N'-bis(trimethylsilyl)benzamidinates o f chromium, manganese, zinc and bismuth is described. The chromium(II) derivative [PhC(NSiM e3)2]2Cr (2) has been char­ acterized by an X-ray structure determination. Treatment o f CpTiCl3 with one equivalent o f N a[PhC (N SiM e3),] • 0.5 Et^O yields the mixed Cp/benzamidinate complex [PhC(NSiM e3)2]CpTiCl2 (9). 
  Reference    Z. Naturforsch. 46b, 1328—1332 (1991); eingegangen am 26. April 1991 
  Published    1991 
  Keywords    N, N'-Bis(trim ethylsilyl)benzam idinates, Chromium, Manganese, Zinc, Bismuth 
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 TEI-XML for    default:Reihe_B/46/ZNB-1991-46b-1328.pdf 
 Identifier    ZNB-1991-46b-1328 
 Volume    46 
8Author    Fausto Calderazzo, Guido Pam, M. Artin Sperrlea, Ulli EnglertbRequires cookie*
 Title    Electron-and Ligand-Transfer Reactions Involving N,N-Dialkylcarbamates. Synthesis and Molecular Structure of V jIf^ -C C sH ^ yC ^ C N t^ H ^ h  
 Abstract    Electron-and ligand-transfer reactions o f low-valent organom etallic com pounds o f titanium and vanadium with N,N-dialkylcarbam ates o f titanium(IV) are reported. The reaction o f VCp2 (Cp = ^-cyclopentadienyl) with T i(0 2C N E t2)4 affords, inter alia, the dimeric vana-dium(III) N ,N-diethylcarbam ato derivative V2Cp2(0 2C N E t2)4 which has been studied by X-ray diffraction methods. Crystal data; triclinic, space group P i; a = 10.802(2), b = 11.004(1), c = 8.960(1) Ä; a = 112.879(9), ß = 102.66(1), y = 102.42(1)°; V = 902.3(6) A 3; Z = 1; F(000) = 368, gcalc = 1.282 g em -3; n = 5.47 cm -1. It consists o f a centrosymmetric dimer, the two vanadium atom s being surrounded by four oxygen atom s o f the bridging N,N-diethylcar-bamato groups and by the cyclopentadienyl ligand. The metal atom exhibits a distorted square-pyramidal coordination geometry with the oxygen atom s occupying the basal plane. The reaction o f TiCp2(CO)2 or Vmes2 (mes = //6-l,3 ,5 -M e3C6H 3) with T i(0 2C N E t2)4 affords Ti(III) and V(III) N,N-diethylcarbam ato derivatives by a simultaneous ligand-and electron-transfer reaction. M agnesium N ,N-diisopropylcarbam ate, M g (0 2CNPr'2)2, has been obtained by a ligand-transfer reaction between M gCp2 and T i(0 2CNPr'2)3. 
  Reference    Z. Naturforsch. 47b, 389 (1992); received A ugust 9 / October 16 1991 
  Published    1992 
  Keywords    N, N-D ialkylcarbam ates, Vanadium, Titanium, Cyclopentadienyl, Electron Transfer 
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 TEI-XML for    default:Reihe_B/47/ZNB-1992-47b-0389.pdf 
 Identifier    ZNB-1992-47b-0389 
 Volume    47 
9Author    H. Möhrle, J. MehrensRequires cookie*
 Title    Reaktivität nitrophenylsubstituierter cyclischer Amine bei Dehydrierungen The Reactivity of Nitrophenyl Substituted Cyclic Amines with Dehydrogenations  
 Abstract    Piperidine and perhydroazepine bearing a 1 -(4-nitrophenyl) substituent were inert to mercury-edta, while the a-pipecoline derivative gave an aminoketone with cleavage of the heterocycle. However the corresponding (2-nitrophenyl) compounds reacted to give respectively a piperidin-2-one, an aminopentanal and an aminohexanone. By an additional substituent in 2'-position the p-nitro compounds underwent dehydrogenation too. With a methyl group resulted a pattern analogous to o-nitro products. A neighbouring hydroxymethyl function enhanced the reaction with formation of benzoxazines and if possible their further oxidized derivatives, the hydroxylactams. 
  Reference    (Z. Naturforsch. 53b, 37 [1998]; eingegangen am 8. Oktober 1997) 
  Published    1998 
  Keywords    Lactam, Iminium Salt, Aminoketone, N, 0-Acetal, Neighbour Group 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0037.pdf 
 Identifier    ZNB-1998-53b-0037 
 Volume    53 
10Author    Toshiyuki Takam, KeisukeN. Akam Ura, M. Ikito Ihara, Hisanobu Wakita, Toshio YamaguchiRequires cookie*
 Title    Raman Scattering and X-ray Diffraction Studies on Zinc(II) Bromide Solutions in Methanol and N,N-Dimethylformamide in the Temperature Range 77-333 K  
 Abstract    n Z i n c (I I) B r o m i d e S o l u t i o n s i n M e t h a n o l a n d N , N -D i m e t h y l f o r m a m i d e i n t h e T e m p e r a t u r e R a n g e 7 7 -3 3 3 K The structure o f zinc(II) brom o com plexes in m ethanol and N,N-dim ethylformam ide (D M F) (molar ratio [solvent]/[ZnBr?] = 10, temperature range 7 7 -3 3 3 K) has been investigated by Raman scattering and X-ray diffraction. In the m ethanol solution symmetric Z n -B r vibrations (vt) o f the dibrom o-and tribrom ozinc(II) com plexes were observed at 209 and 184 c m " 1, respectively. With decreasing temperature the intensity o f the vx band decreased for the dibrom o and increased for the tribromo complex. In addition, the Vj band for the tetrabromo complex appeared in the supercooled and glassy methanol solutions. In the D M F solution only one band, assigned to both the dibrom o-and tribromozinc(II) com plexes, was observed. Its intensity did not change with temper­ ature. The X-ray diffraction data revealed that the average number of Z n -B r interactions within the zinc (II) bromo com plexes does not change with temperature while the number of nonbonding Br • • • Br interactions within the com plexes increases from 1.5 at 298 K to 1.9 at 243 K for the methanol solution and from 1.3 at 298 K to 1.8 at 243 K for the D M F solution. These Raman and X-ray results have confirmed that in both m ethanol and D M F solutions at high temperatures the dibrom o species is predominantly formed, whereas at low temperatures the tribromo com plex is favored, the tetrabromo species being formed only in the supercooled and glassy m ethanol solutions. The temperature dependent equilibrium shifts of the zinc(II) bromo complexes in the methanol and D M F solutions are discussed together with previously reported results for the aqueous phase. 
  Reference    Z. Naturforsch. 49a, 1119 (1994); received O ctober 15 1994 
  Published    1994 
  Keywords    Raman spectroscopy, X-ray diffraction, Zinc(II) bromide, M ethanol, N, N -D im ethyl-formamide 
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 TEI-XML for    default:Reihe_A/49/ZNA-1994-49a-1119.pdf 
 Identifier    ZNA-1994-49a-1119 
 Volume    49 
11Author    Makoto Koide, Shin-Ichi IshiguroRequires cookie*
 Title     
 Abstract    h e r m o d y n a m ic s a n d S t r u c t u r e o f I s o th io c y a n a te C o m p le x e s o f M a n g a n e s e (I I) , C o b a l t(I I) a n d Z i n c (I I) Io n s in N ,N -D im e th y la c e ta m id e Dedicated to Prof. Dr. Ohtaki on his occasion of 60th birthday The complexation of manganese (II), cobalt (II) and zinc(II) with thiocyanate ions has been studied in N,N-dimethylacetamide (DMA) by calorimetry and spectrophotometry at 298 K. In these metal systems the formation of a series of four isothiocyanato complexes, [M(NCS)J<2-n)+ (n = 1-^4; M = Mn, Co, and Zn) was established, and their formation constants, enthalpies and entropies were determined. Interestingly, the complexation behavior in DMA is significantly different from that in N,N-dimethylformamide (DMF), despite of the similarity of the physicochemical properties of these solvents. The complexation is indeed enhanced significantly in DMA over DMF and is more exothermic in the former solvent. Furthermore, with cobalt(II) an octahedral to tetrahedral coordi­ nation geometry change was found to occur in DMA at an earlier step of complexation than in DMF. These results suggest that six-coordination of DMA molecules to a metal ion is severely sterically hindered. 
  Reference    Z. Naturforsch. 50a, 11—17 (1995); received September 26 1994 
  Published    1995 
  Keywords    Thiocyanato complexes, Transition metal(II) ions, N, N-dimethylacetamide, Calorime­ try, Spectrophotometry 
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 TEI-XML for    default:Reihe_A/50/ZNA-1995-50a-0011.pdf 
 Identifier    ZNA-1995-50a-0011 
 Volume    50 
12Author    Kenji Nomiya, Nahoko Wako, Tomoko Komiyama, Makoto MiwaRequires cookie*
 Title    Catalytic Oxygenation of 3-Methylindole by Co(II)-Schiff Base Planar Complexes  
  Reference    Z. Naturforsch. 34b, 442—447 (1979); received November 13 1978 
  Published    1979 
  Keywords    Catalytic Oxygenation, 3-Methylindole, N, N'-Ethylenebis(acetylacetoniminato)Co(II), Manometric Observation, X H NMR 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0442.pdf 
 Identifier    ZNB-1979-34b-0442 
 Volume    34 
13Author    Walter Dannecker, HansWerner MüllerRequires cookie*
 Title    Ureadiid-Derivate von Mangan(I)-und Rhemum(I)-carbonylen Ureadiide Derivatives of Manganese (I) and Rhenium (I) Car bony Is  
  Reference    Z. Naturforsch. 37b, 318—323 (1982); eingegangen am 3. November 1981 
  Published    1982 
  Keywords    N, N'-Diorganyl-ureadiides, Monodentate Ligand (N-Coordination), Bidentate Ligand (N, 0-Coordination) 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0318.pdf 
 Identifier    ZNB-1982-37b-0318 
 Volume    37 
14Author    Evamarie Hey, Christina Ergezinger, Kurt DehnickeRequires cookie*
 Title    Die Reaktion von N  
 Abstract    ,N,N'-Tris(trimethylsilyI)benzamidin mit Kupfer(II)chlorid. Kristallstruktur von {C 6 H 5 -C(NSiMe 3) 2 CuCl [C 6 H 5 -C(NSiMe 3)(NHSiMe 3)]} The Reaction of N,N,N'-Tris(trimethylsilyl)benzamidine with Copper(II) Chloride. Crystal Structure of {C 6 H 5 —C(NSiMe 3)->CuCl • [C 6 H 5 -C(NSiMe 3)(NHSiMe 3)]} 
  Reference    Z. Naturforsch. 43b, 1679—1682 (1988); eingegangen am 27. Juni 1988 
  Published    1988 
  Keywords    N, N'-Bis(trimethylsilyl)benzamidinato-copper Chloride-N, N'-bis(trimethylsilyl)benzamidine Adduct, Synthesis, IR Spectrum, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1679_n.pdf 
 Identifier    ZNB-1988-43b-1679_n 
 Volume    43 
15Author    JohnDavid Kildea, Wolfgang Hiller, Beatrice Borgsen, Kurt DehnickeRequires cookie*
 Title    Synthese, IR-Spektrum und Kristallstruktur des Amidinatokomplexes [N a(15-K rone-5)][Ph—C(NSiM e3)2SnCl3F] Synthesis, IR Spectrum, and Crystal Structure of the Amidinato Complex [N a(15-Crow n-5)][Ph-C(N SiM e3)2SnCl3F]  
  Reference    Z. Naturforsch. 44b, 889 (1989); eingegangen am 30. März 1989 
  Published    1989 
  Keywords    N, N '-Bis(trim ethylsilyl)am idinato C om plex, Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/44/ZNB-1989-44b-0889.pdf 
 Identifier    ZNB-1989-44b-0889 
 Volume    44 
16Author    H. Möhrle, M. JeandréeRequires cookie*
 Title    ,3-Dioxolane von N-substituierten 4-Piperidonen als Dehydrierungssubstrat 1,3-Dioxolanes of N-Substituted 4-Piperidones as Substrates for Dehydrogenations  
 Abstract    The applicability of ketals was examined for masking the carbonyl group in N-tertiary 4-piperidones during the dehydrogenation using mercury-edta. Various 1,3-dioxolanes showed a different behaviour in dependence on the N-substituent. With simple aliphatic moieties mainly dehydrogenated but hydrolyzed products were received. These enaminones were also available from the dehydrogenations of the corresponding 4-piperidones. Similar applied to para-acyl-aromatic substituted derivatives but with less yields. Aromatic substituents bearing a neighbour group on ortho-position with participation gave rise to different oxidation products partially with preservation of the ketal structure. 
  Reference    (Z. Naturforsch. 52b, 72—78 [1997]; eingegangen am 23. August 1996) 
  Published    1997 
  Keywords    Ketals, Enaminones, N, 0-A cetals, Lactams, Dehydrogenation with Hg-EDTA Complex 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0072.pdf 
 Identifier    ZNB-1997-52b-0072 
 Volume    52 
17Author    Andreas Böhm, Kurt Polborn, Karlheinz Sünkel, Wolfgang BeckRequires cookie*
 Title    Metallkomplexe mit biologisch wichtigen Liganden, CIV [1]. or/Zio-Palladierte Komplexe von N,N-DimethyI-C-phenyl-glycinmethylester. Synthese von a-Aminosäure-Derivaten durch Insertion von Isocyaniden, CO, Alkenen und Alkinen in die Pd-C-Bindung Metal Complexes of Biologically Important Ligands, CIV [ 1]. o/t/20-Palladated Complexes of N,N-Dimethyl-C-phenylglycine-methylester. Synthesis of ct-Amino Acid Derivatives by Insertion of Isocyanides, CO, Alkenes, and Alkynes into the Pd-C Bond  
 Abstract    -phenylglycinemethylester reacts with Pd(OAc)2 in acetic acid to give the orthopalladated, acetato bridged complex 1. Treatment of 1 with sodium halide affords the chlo-ro, bromo, and iodo bridged compounds [Me2N C (H)(C 02Me)C6H4PdX]2 (2a -c) (X = halide). From 2a and 1,1 '-bis(diphenylphosphino)ferrocene the phosphine bridged trinuclear complex 3 is obtained. Substitution of the amine ligand of 2a by the phosphino group is observed for the reaction of 2a with Ph2PC(Me)C(Me)PPh2. Insertion of 2,6-dimethyl-phenylisocyanide, CO, alkyl-vinyl-ketones, and diphenylacetylene into the Pd-C bond o f 2a -c provides the ortho­ substituted organic and organometallic derivatives of phenylglycine 6a -c, 7, 8a -b and 9a -c. The crystal structures of 1, 4a, 6a, 7 and 9a were determined by X-ray diffraction. 
  Reference    Z. Naturforsch. 53b, 448—458 (1998); eingegangen am 19. Dezember 1997 
  Published    1998 
  Keywords    Palladium(II) Complexes, ortho-Palladation, N, N-Dimethyl-C-phenylglycine, Insertion Reactions N, N-Dimethyl-C 
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 Identifier    ZNB-1998-53b-0448 
 Volume    53 
18Author    JonesRequires cookie*
 Title    Polysulfonylamine, CV [1] Die ersten N,N-disulfonylierten Sulfinsäureamide: Synthese und Kristallstrukturen von R S ( 0 )-N (S 0 2Me)2 (R = Me, CC13)  
 Abstract    P o ly su lfo n y lam in es, C V [1] T h e F irst N ,N -D isu lfo n y lated S ulfinic A m id es: S y nthesis a n d C ry sta l S tru c tu re s o f R S (0) -N (S 0 2M e)2 (R = M e, CC13) M a rtin a N äv e k e, A rm a n d B lasc h ette* , P e te r G. The novel sulfinamides R S (0) -N (S 0 2M e)2, where R = Me (la) or CC13 (lb), were ob­ tained by treating the corresponding sulfinyl chlorides with Me3S iN (S 02Me)2 or AgN-(S 0 2Me)2, respectively. A presumedly ionic 1:1 adduct of lb with 4-dimethylaminopyridine was isolated and analytically characterized. In the crystals of la (monoclinic, space group P2\!ri) and lb (monoclinic, P l j c) , the molecules feature approximately planar NS3 moieties, unusually long S (0) -N bonds and, in the case of lb, an extremely long S (0) -C bond [for la and lb, in order: sum of bond angles at nitrogen 359.5 and 357.1°, S (0) -N 178.2(2) and 173.6(2) pm, S (0) -C 178.8(2) and 194.1(2) pm]. In both molecular structures, an attractive S (0) --0 1,4-interaction leads to a 7.3° discrepancy in the S (0) -N -S 0 2 angles. The crystal packing of la displays a tape (double-chain) motif generated by two prominent intermolecu-lar C -H -O interactions involving one M e S 0 2 group and the sulfinyl oxygen atoms of two adjacent molecules, whereas in lb the molecules are associated into parallel chains via a bonding C l-"0(sulfonyl) interaction. 
  Reference    Z. Naturforsch. 53b, 734—741 (1998); eingegangen am 6. April 1998 
  Published    1998 
  Keywords    N, N-Bis(organosulfonyl)sulfinamides, Synthesis, Crystal Structure, Long S ( 0 ) -N Bond 
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 Identifier    ZNB-1998-53b-0734 
 Volume    53 
19Author    Hans Bock, N. Orbert, N. Agel, C. Hristian, N. ÄtherRequires cookie*
 Title    Wechselwirkungen in Molekülkristallen, 147 [1, 2 ]. Isostrukturelle Wirt/Gast-Einschluß-Verbindungen von N,N'-Ditosyl- p-phenylendiamin mit Aceton, Cyclopentanon, Cyclopent-2-en-l-on, 1,3-Dioxolan, Tetrahydrofuran und 2,5-Dihydrofuran  
 Abstract    Interactions in M olecular Crystals, 147 [1, 2], Isostructural H ost/G uest-Inclusion Com pounds o f N ,N'-D itosyl-/?-phenylenediam ine w ith A cetone, C yclopentanone, C yclopent-2-ene-l-one, 1,3-Dioxolane, Tetrahydro­ furane, and 2,5-D ihydrofurane H errn P ro fe sso r M a n fre d E igen g e w id m e t 
  Reference    Z. Naturforsch. 53b, 1401—1412 (1998); eingegangen am 19. August 1998 
  Published    1998 
  Keywords    N, N'-Ditosyl-p-phenylenediamine, Inclusion Compounds, Crystal Growth, Structures, Host/Guest-Relations 
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 Identifier    ZNB-1998-53b-1401 
 Volume    53 
20Author    Hans Bock, N. Orbert, N. Agel, C. Hristian, N. ÄtherRequires cookie*
 Title    Wechselwirkungen in Molekülkristallen, 149 [1 -3]. Wirt/Gast-Einschlußverbindungen von NjN'-Ditosyl-p-phenylendiamin: Die Wasserstoffbrücken-Addukte mit Morpholin; Pyridin, N,N-Dimethylformamid und Dimethylsulfoxid  
 Abstract    Interactions in M olecular C rystals, 149 [1 -3]. H ost/G uest-Inclusion Com pounds of N ,N'-D itosyl-/?-phenylenediam ine: The H ydrogen Bonded Adducts with M orpholine, Pyridine, N ,N -D im ethylform am ide, and D im ethylsulfoxide H errn P ro fe sso r M a n fred E igen g e w id m e t 
  Reference    Z. Naturforsch. 53b, 1425—1439 (1998); eingegangen am 19. August 1998 
  Published    1998 
  Keywords    N, N'-Ditosyl-/?-phenylenediamine, Inclusion Compounds, Hydrogen Acceptor and Donor Guest Molecules, Crystal Growth, Structures 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1425.pdf 
 Identifier    ZNB-1998-53b-1425 
 Volume    53 
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